Learn · MIT OpenCourseWare

Two curves and a few rectangles.

Course2.4325 lectures

Advanced Thermodynamics

Prof. Gian Paolo Beretta · Massachusetts Institute of Technology

Start with lecture 1 At MIT OpenCourseWare

About

This course is a self-contained concise review of general thermodynamics concepts, multicomponent equilibrium properties, chemical equilibrium, electrochemical potentials, and chemical kinetics, as needed to introduce the methods of nonequilibrium thermodynamics and to provide a unified understanding of phase equilibria, transport, and nonequilibrium phenomena useful for future energy and climate engineering technologies. Applications include second-law efficiencies and methods to allocate primary energy consumptions and CO₂ emissions in cogeneration and hybrid power systems, minimum work of separation, maximum work of mixing, osmotic pressure and membrane equilibria, metastable states, spinodal decomposition, and Onsager’s near-equilibrium reciprocity in thermodiffusive, thermoelectric, and electrokinetic cross effects.

Lectures

Lecture Videos

  1. Lecture 1: Definitions of System, Property, State, and Weight Process; First Law and Energy Video
  2. Lecture 2: Second Law and Entropy; Adiabatic Availability; Maximum Entropy Principle Video
  3. Lecture 3: Energy vs Entropy Diagrams to Represent Equilibrium and Nonequilibrium States Video
  4. Lecture 4: Temperature, Pressure, Chemical Potentials; the Clausius Statement of the Second Law Video
  5. Lecture 5: Definition of Heat Interaction; First and Second Law Efficiencies Video
  6. Lecture 6: Free Energies, Available Energies, and Stability Conditions Video
  7. Lecture 7: Availability Functions and the LeChatelier-Braun Principle Video
  8. Lecture 8: Few versus Many Particles: The Euler Relation; Review of Various Forms of Exergy (Part I) Video
  9. Lecture 9: Minimum Work of Partitioning Small Systems; The Gibbs Phase Rule; The Van der Waals Model Video
  10. Lecture 10: Review of Various Forms of Exergy (Part II); Allocation of Consumptions in Cogeneration Video
  11. Lecture 11: Allocation in Hybrid Power Production; Chemical Potentials and Partial Pressures Video
  12. Lecture 12: Ideal Mixture Behavior; Work from Reversible Mixing; Entropy of Irreversible Mixing Video
  13. Lecture 13: The Gibbs Paradox; Shannon Information Entropy; Single Quantum Particle in a Box Video
  14. Lecture 14: Ideal Solution Model; Osmotic Pressure; Blue Energy; Minimum Work of Separation Video
  15. Lecture 15: Stratification in Gas and Liquid Mixtures; Liquid-Vapor Spinodal Decomposition Video
  16. Lecture 16: Liquid-Vapor Equilibria in Mixtures; Ideal and Excess Chemical Potentials Video
  17. Lecture 17: Liquid-Liquid Spinodal Decomposition; Introduction to Systems with Chemical Reactions Video
  18. Lecture 18: Properties of Reaction; Heating Values and Exergy of Fuels; Adiabatic Flame Temperature Video
  19. Lecture 19: Affinity and Nonequilibrium Law of Mass Action; Potential Energy Surface Video
  20. Lecture 20: Chemical Kinetics; The Arrhenius Law; Degree of Disequilibrium; Principle of Detailed Balance Video
  21. Lecture 21: Introduction to Nonequilibrium Theory; Onsager Reciprocity and Maximum Entropy Production Video
  22. Lecture 22: Definition of “Heat&Diffusion” Interaction; Diffusive and Convective Fluxes Video
  23. Lecture 23: Direct and Cross Effects; General Principles of Entropy Production; The Fourth Law Video
  24. Lecture 24: Relative Diffusion Fluxes; Thermoelectric Effects Video
  25. Lecture 25: Thermodiffusive Effects; Multicomponent Transport Video

Syllabus and materials

At MIT OpenCourseWare, as the course publishes them.

Credits and licence

Institution
Massachusetts Institute of Technology
Department
Mechanical Engineering
Teacher
Prof. Gian Paolo Beretta
Term
Spring 2024
Level
Graduate
Language
English
Subjects
Physics, Chemistry, Engineering, Earth and environment
Source
MIT OpenCourseWare
Licence
CC BY-NC-SA 4.0, as MIT OpenCourseWare states it. Non-commercial use only. MIT OpenCourseWare's terms
Attribution
Prof. Gian Paolo Beretta. Advanced Thermodynamics. Spring 2024. Massachusetts Institute of Technology: MIT OpenCourseWare, https://ocw.mit.edu/. License: Creative Commons BY-NC-SA.
Who can watch
MIT OpenCourseWare gives no rating. Invisible Network shows it to Tweens profiles and older, judged from what the source says about it. How courses are placed