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Lecture 23 of 25Lecture Videos

Lecture 23: Direct and Cross Effects; General Principles of Entropy Production; The Fourth Law

Prof. Gian Paolo Beretta · Massachusetts Institute of Technology

At MIT OpenCourseWare Transcript

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From
Advanced Thermodynamics, Massachusetts Institute of Technology (at MIT OpenCourseWare)
Licence
CC BY-NC-SA 4.0, as MIT OpenCourseWare states it. Non-commercial use only.
Attribution
Prof. Gian Paolo Beretta. Advanced Thermodynamics. Spring 2024. Massachusetts Institute of Technology: MIT OpenCourseWare, https://ocw.mit.edu/. License: Creative Commons BY-NC-SA.
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All the lectures

  1. Lecture 1: Definitions of System, Property, State, and Weight Process; First Law and Energy Video
  2. Lecture 2: Second Law and Entropy; Adiabatic Availability; Maximum Entropy Principle Video
  3. Lecture 3: Energy vs Entropy Diagrams to Represent Equilibrium and Nonequilibrium States Video
  4. Lecture 4: Temperature, Pressure, Chemical Potentials; the Clausius Statement of the Second Law Video
  5. Lecture 5: Definition of Heat Interaction; First and Second Law Efficiencies Video
  6. Lecture 6: Free Energies, Available Energies, and Stability Conditions Video
  7. Lecture 7: Availability Functions and the LeChatelier-Braun Principle Video
  8. Lecture 8: Few versus Many Particles: The Euler Relation; Review of Various Forms of Exergy (Part I) Video
  9. Lecture 9: Minimum Work of Partitioning Small Systems; The Gibbs Phase Rule; The Van der Waals Model Video
  10. Lecture 10: Review of Various Forms of Exergy (Part II); Allocation of Consumptions in Cogeneration Video
  11. Lecture 11: Allocation in Hybrid Power Production; Chemical Potentials and Partial Pressures Video
  12. Lecture 12: Ideal Mixture Behavior; Work from Reversible Mixing; Entropy of Irreversible Mixing Video
  13. Lecture 13: The Gibbs Paradox; Shannon Information Entropy; Single Quantum Particle in a Box Video
  14. Lecture 14: Ideal Solution Model; Osmotic Pressure; Blue Energy; Minimum Work of Separation Video
  15. Lecture 15: Stratification in Gas and Liquid Mixtures; Liquid-Vapor Spinodal Decomposition Video
  16. Lecture 16: Liquid-Vapor Equilibria in Mixtures; Ideal and Excess Chemical Potentials Video
  17. Lecture 17: Liquid-Liquid Spinodal Decomposition; Introduction to Systems with Chemical Reactions Video
  18. Lecture 18: Properties of Reaction; Heating Values and Exergy of Fuels; Adiabatic Flame Temperature Video
  19. Lecture 19: Affinity and Nonequilibrium Law of Mass Action; Potential Energy Surface Video
  20. Lecture 20: Chemical Kinetics; The Arrhenius Law; Degree of Disequilibrium; Principle of Detailed Balance Video
  21. Lecture 21: Introduction to Nonequilibrium Theory; Onsager Reciprocity and Maximum Entropy Production Video
  22. Lecture 22: Definition of “Heat&Diffusion” Interaction; Diffusive and Convective Fluxes Video
  23. Lecture 23: Direct and Cross Effects; General Principles of Entropy Production; The Fourth Law Video
  24. Lecture 24: Relative Diffusion Fluxes; Thermoelectric Effects Video
  25. Lecture 25: Thermodiffusive Effects; Multicomponent Transport Video