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Course10410806240 lectures

Introduction to Organometallic Chemistry

Prof. A.G. Samuelson · IISc Bangalore

Start with lecture 1 At NPTEL

Lectures

Introduction

  1. Introduction to Organometallic chemistry Video

C1 ligands and simple reactions

  1. Metal carbonyl complexes Video
  2. Metal carbonyls –Part II Video
  3. Ligand substitution reactions Video
  4. Substitutes for carbonyl ligands Video
  5. Carbene complexes Video
  6. Carbene complexes continued Video
  7. Non-Carbon Ancillary ligands Video
  8. Non-Carbon Ancillary ligands continued Video
  9. Metal alkyl complexes Video
  10. Ligand Insertion Reactions Video

η m (m=even) ligands

  1. Metal alkene complexes Video
  2. Alkynes ?2 bonding Video
  3. Metal dihydrogen and hydrides Video
  4. Migratory Insertion reaction with alkynes Video
  5. ηm (m=4 dienes and m=2n,polyenes) Video

Reactions with oxidation state change

  1. Oxidative addition & Vaskas complex mechanism Video
  2. Reductive elimination Video
  3. Reductive Elimination mechanism Video
  4. Oxidative coupling with C-C bond formation Video
  5. Metathesis reactions Video

η m (m=odd) ligands

  1. Metal-allyls - ? 3 complexes-synthesis, bonding Video
  2. Metal-allyls - η 3 complexes-fluxionality, reactivity Video
  3. C-C single bond forming reactions Video

Metallocenes

  1. ? 5 Cyclopentadienyl - complexes Video
  2. η6 arene Metal complexes Video
  3. Half sandwich complexes Video
  4. Reactivity changes in coordinated ligands Video

Dynamics and structures of organometallic compounds

  1. The isolobal analogy Video
  2. Fluxional Properties of Organometallics Video
  3. Quantifying Steric and electronic factors Video

Useful catalytic and Stoichiometric reactions

  1. Hydrogenation reactions Video
  2. Addition of HX to olefins Video
  3. Reactions with CO insertion Video
  4. Organometallics promoted C-X coupling Video
  5. Organometallic polymerization Video
  6. C-H activation Video

Applications of organometallic chemistry

  1. Asymmetric Catalysis Video
  2. Medicinal applications of organometallic complexes Video
  3. Special Properties and Applications Video

Syllabus and materials

At NPTEL, as the course publishes them.

Credits and licence

Institution
IISc Bangalore
Department
Chemistry and Biochemistry
Teacher
Prof. A.G. Samuelson
Level
Undergraduate
Language
English
Subjects
Chemistry
Source
NPTEL
Licence
CC BY-NC-SA, as NPTEL states it. Non-commercial use only. NPTEL's terms
Attribution
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