Learn · Introduction to Organometallic Chemistry
Lecture 8 of 40C1 ligands and simple reactions
Non-Carbon Ancillary ligands
Prof. A.G. Samuelson · IISc Bangalore
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- Introduction to Organometallic Chemistry, IISc Bangalore (at NPTEL)
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All the lectures
- Introduction to Organometallic chemistry
- Metal carbonyl complexes
- Metal carbonyls –Part II
- Ligand substitution reactions
- Substitutes for carbonyl ligands
- Carbene complexes
- Carbene complexes continued
- Non-Carbon Ancillary ligands
- Non-Carbon Ancillary ligands continued
- Metal alkyl complexes
- Ligand Insertion Reactions
- Metal alkene complexes
- Alkynes ?2 bonding
- Metal dihydrogen and hydrides
- Migratory Insertion reaction with alkynes
- ηm (m=4 dienes and m=2n,polyenes)
- Oxidative addition & Vaskas complex mechanism
- Reductive elimination
- Reductive Elimination mechanism
- Oxidative coupling with C-C bond formation
- Metathesis reactions
- Metal-allyls - ? 3 complexes-synthesis, bonding
- Metal-allyls - η 3 complexes-fluxionality, reactivity
- C-C single bond forming reactions
- ? 5 Cyclopentadienyl - complexes
- η6 arene Metal complexes
- Half sandwich complexes
- Reactivity changes in coordinated ligands
- The isolobal analogy
- Fluxional Properties of Organometallics
- Quantifying Steric and electronic factors
- Hydrogenation reactions
- Addition of HX to olefins
- Reactions with CO insertion
- Organometallics promoted C-X coupling
- Organometallic polymerization
- C-H activation
- Asymmetric Catalysis
- Medicinal applications of organometallic complexes
- Special Properties and Applications