Learn · Freshman Organic Chemistry I

Lecture 10 of 37Lecture 10

Reality and the Orbital Approximation

J. Michael McBride · Yale University

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Freshman Organic Chemistry I, Yale University (at Open Yale Courses)
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All the lectures

  1. How Do You Know? Audio
  2. Force Laws, Lewis Structures and Resonance Audio
  3. Double Minima, Earnshaw's Theorem and Plum-Puddings Audio
  4. Coping with Smallness and Scanning Probe Microscopy Audio
  5. X-Ray Diffraction Audio
  6. Seeing Bonds by Electron Difference Density Audio
  7. Quantum Mechanical Kinetic Energy Audio
  8. One-Dimensional Wave Functions Audio
  9. Chladni Figures and One-Electron Atoms Audio
  10. Reality and the Orbital Approximation Audio
  11. Orbital Correction and Plum-Pudding Molecules Audio
  12. Overlap and Atom-Pair Bonds Audio
  13. Overlap and Energy-Match Audio
  14. Checking Hybridization Theory with XH3 Audio
  15. Chemical Reactivity: SOMO, HOMO, and LUMO Audio
  16. Recognizing Functional Groups Audio
  17. Reaction Analogies and Carbonyl Reactivity Audio
  18. Amide, Carboxylic Acid and Alkyl Lithium Audio
  19. Oxygen and the Chemical Revolution (Beginning to 1789) Audio
  20. Rise of the Atomic Theory (1790-1805) Audio
  21. Berzelius to Liebig and Wöhler (1805-1832) Audio
  22. Radical and Type Theories (1832-1850) Audio
  23. Valence Theory and Constitutional Structure (1858) Audio
  24. Determining Chemical Structure by Isomer Counting (1869) Audio
  25. Models in 3D Space (1869-1877); Optical Isomers Audio
  26. Van't Hoff's Tetrahedral Carbon and Chirality Audio
  27. Communicating Molecular Structure in Diagrams and Words Audio
  28. Stereochemical Nomenclature; Racemization and Resolution Audio
  29. Preparing Single Enantiomers and the Mechanism of Optical Rotation Audio
  30. Esomeprazole as an Example of Drug Testing and Usage Audio
  31. Preparing Single Enantiomers and Conformational Energy Audio
  32. Stereotopicity and Baeyer Strain Theory Audio
  33. Conformational Energy and Molecular Mechanics Audio
  34. Sharpless Oxidation Catalysts and the Conformation of Cycloalkanes Audio
  35. Understanding Molecular Structure and Energy through Standard Bonds Audio
  36. Bond Energies, the Boltzmann Factor and Entropy Audio
  37. Potential Energy Surfaces, Transition State Theory and Reaction Mechanism Audio