Learn · Chemical Engineering Thermodynamics
Lecture 3 of 63Week 1
Postulates of thermodynamics - I
Prof. Jayant K. Singh · IIT Kanpur
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- Chemical Engineering Thermodynamics, IIT Kanpur (at NPTEL)
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All the lectures
- Introduction
- Measurability and controllability of energy
- Postulates of thermodynamics - I
- Postulates of thermodynamics - II
- Definition of intensive variables and driving forces for temperature and pressure flow
- Driving force for the matter flow
- Basic properties, phase diagram, and thermodynamic table
- Work, and heat
- First law of thermodynamics for closed system: Ideal gas behavior
- First law of thermodynamics: Example 1
- First law of thermodynamics for open system
- First law of thermodynamics: Example 2
- The second law of the thermodynamics: Review
- Carnot cycle and thermodynamic temperature
- The concept of entropy
- Maximum work and entropy of ideal gas
- Power cycles and examples
- Mathematical properties of fundamental equations
- Generalized thermodynamic potential -I
- Generalized thermodynamic potential -II
- Multivariable Calculus
- Maxwell’s relations and examples
- Jacobian method and its applications
- Equilibrium and stability-I
- Equilibrium and stability-II
- Stability criteria
- Intrinsic stability of thermodynamic system
- Phase transitions
- Clapeyron Equation and Vapour Pressure Correlations
- Equation of State
- Equation of state (Continue)
- Repulsive Interaction
- Fugacity
- Thermodynamics of mixtures
- Partial molar properties and examples
- Examples of partial molar properties for real processes
- Obtaining the partial molar properties from experimental data
- Partial molar properties of ideal gas mixtures
- Chemical potential of ideal gas mixtures
- Fugacity coefficient in terms of measurable properties
- Fugacity coefficient for mixtures
- Fugacity coefficient for ideal mixtures
- Activity coefficient for mixtures
- Gibbs - Duhem relations and its impacts on the activity
- Excess Gibbs free energy model
- Two suffix Margules equation
- Excess Gibbs free energy model - II
- Vapor Liquid Equilibria
- Vapor Liquid Equilibria (examples)
- Vapor Liquid Equilibria (non-ideal mixtures)
- Vapor Liquid Equilibria (non-ideal mixtures - II)
- Azeotropes
- Azeotrope (binary mixture)
- Liquid-Liquid equilibria -1
- liquid-liquid equilibria (continue) and solid-liquid equilibria
- Solid-liquid equilibria (continue)
- Solid-liquid equilibria examples and properties
- Examples of boiling point elevation
- Solubility of gases in the liquid
- Chemical reaction equilibria
- Chemical reaction equilibria - II
- Chemical reaction equilibria - III
- Chemical reaction equilibria - IV