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Course10310415163 lectures

Chemical Engineering Thermodynamics

Prof. Jayant K. Singh · IIT Kanpur

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About

This course covers the foundation of classical thermodynamics in the form of postulates, and later their applications to open and close systems, criteria of stability and equilibria, the equation of states, properties of pure fluids and mixtures, theories and model of phase equilibrium, and chemical reaction equilibrium. The major focus in the first half of the course would be to build a strong foundation in the subject. The second part of the course will emphasis the application of the thermodynamics on chemical engineering problems related to phase equilibria.

INTENDED AUDIENCE : Engineering Students/Faculty

PREREQUISITES : Engineering Thermodynamics

INDUSTRY SUPPORT : All chemical engineering-based industries, Bechtel, UOP, EIL, Reliance, Indian Oil, ONGC, Unilever

Lectures

Week 1

  1. Introduction YouTube
  2. Measurability and controllability of energy YouTube
  3. Postulates of thermodynamics - I YouTube
  4. Postulates of thermodynamics - II YouTube
  5. Definition of intensive variables and driving forces for temperature and pressure flow YouTube
  6. Driving force for the matter flow YouTube

Week 2

  1. Basic properties, phase diagram, and thermodynamic table YouTube
  2. Work, and heat YouTube
  3. First law of thermodynamics for closed system: Ideal gas behavior YouTube
  4. First law of thermodynamics: Example 1 YouTube
  5. First law of thermodynamics for open system YouTube
  6. First law of thermodynamics: Example 2 YouTube

Week 3

  1. The second law of the thermodynamics: Review YouTube
  2. Carnot cycle and thermodynamic temperature YouTube
  3. The concept of entropy YouTube
  4. Maximum work and entropy of ideal gas YouTube
  5. Power cycles and examples YouTube

Week 4

  1. Mathematical properties of fundamental equations YouTube
  2. Generalized thermodynamic potential -I YouTube
  3. Generalized thermodynamic potential -II YouTube
  4. Multivariable Calculus YouTube
  5. Maxwell’s relations and examples YouTube
  6. Jacobian method and its applications YouTube

Week 5

  1. Equilibrium and stability-I YouTube
  2. Equilibrium and stability-II YouTube
  3. Stability criteria YouTube
  4. Intrinsic stability of thermodynamic system YouTube
  5. Phase transitions YouTube

Week 6

  1. Clapeyron Equation and Vapour Pressure Correlations YouTube
  2. Equation of State YouTube
  3. Equation of state (Continue) YouTube
  4. Repulsive Interaction YouTube

Week 7

  1. Fugacity YouTube
  2. Thermodynamics of mixtures YouTube
  3. Partial molar properties and examples YouTube
  4. Examples of partial molar properties for real processes YouTube
  5. Obtaining the partial molar properties from experimental data YouTube

Week 8

  1. Partial molar properties of ideal gas mixtures YouTube
  2. Chemical potential of ideal gas mixtures YouTube
  3. Fugacity coefficient in terms of measurable properties YouTube
  4. Fugacity coefficient for mixtures YouTube
  5. Fugacity coefficient for ideal mixtures YouTube

Week 9

  1. Activity coefficient for mixtures YouTube
  2. Gibbs - Duhem relations and its impacts on the activity YouTube
  3. Excess Gibbs free energy model YouTube
  4. Two suffix Margules equation YouTube
  5. Excess Gibbs free energy model - II YouTube

Week 10

  1. Vapor Liquid Equilibria YouTube
  2. Vapor Liquid Equilibria (examples) YouTube
  3. Vapor Liquid Equilibria (non-ideal mixtures) YouTube
  4. Vapor Liquid Equilibria (non-ideal mixtures - II) YouTube
  5. Azeotropes YouTube
  6. Azeotrope (binary mixture) YouTube

Week 11

  1. Liquid-Liquid equilibria -1 YouTube
  2. liquid-liquid equilibria (continue) and solid-liquid equilibria YouTube
  3. Solid-liquid equilibria (continue) YouTube
  4. Solid-liquid equilibria examples and properties YouTube
  5. Examples of boiling point elevation YouTube

Week 12

  1. Solubility of gases in the liquid YouTube
  2. Chemical reaction equilibria YouTube
  3. Chemical reaction equilibria - II YouTube
  4. Chemical reaction equilibria - III YouTube
  5. Chemical reaction equilibria - IV YouTube

Syllabus and materials

At NPTEL, as the course publishes them.

Credits and licence

Institution
IIT Kanpur
Department
Chemical Engineering
Teacher
Prof. Jayant K. Singh
Level
Undergraduate
Language
English
Subjects
Chemistry, Engineering
Source
NPTEL
Licence
CC BY-NC-SA, as NPTEL states it. Non-commercial use only. NPTEL's terms
Attribution
NPTEL states: "Distributed under Creative Commons Attribution-ShareAlike / CC BY - NC - SA", beside a BY-NC-SA badge.
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