Learn · Electrochemical impedance Spectroscopy
Lecture 19 of 53Week 4
Zero/pole representation, Rt and Rp
Prof. S. Ramanathan · IIT Madras
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- From
- Electrochemical impedance Spectroscopy, IIT Madras (at NPTEL)
- Licence
- CC BY-NC-SA, as NPTEL states it. Non-commercial use only.
- Attribution
- NPTEL states: "Distributed under Creative Commons Attribution-ShareAlike / CC BY - NC - SA", beside a BY-NC-SA badge.
- Who can watch
- Tweens profiles and older. How courses are placed
All the lectures
- Detailed Syllabus
- Electrochemistry, double layer, 3 electrode systems, supporting electrolyte
- Rate constant, concept of impedance, Z of electrical elements, differential impedance
- Time domain results
- Graphical representation of data (Complex plane, Bode)
- Introduction to other techniques
- Tutorial 01
- Type of analyzers, single and multi sine
- FFT details, frequency range and resolution, cross correlation
- Multi sine, odd harmonic, non-harmonics, crest factor, spectral leakage
- Windowing
- Tutorial 02
- Introduction to KKT
- Linearity, causality, stability, impedance vs. admittance, measurement model
- Linear KKT illustration
- Tutorial 03
- Introduction to EEC, Choice of circuits, confidence intervals, AIC
- EEC fitting, initial values, distinguishability
- Zero/pole representation, Rt and Rp
- Maxwell, Voigt, Ladder circuits, choice of initial values illustrated
- Tutorial 04
- Simple electron transfer reaction
- Two step reaction with an intermediate (1 of 3)
- Two step reaction with an intermediate (2 of 3)
- Two step reaction with an intermediate (3 of 3)
- E-EAR reaction, negative resistance (1 of 2)
- E-EAR reaction, negative resistance (2 of 2)
- Three step reaction with two adsorbed intermediates
- Catalytic mechanism.
- Examples with Frumkin or Temkin isotherms
- Challenges in RMA
- Patterns reported in experiments
- Warburg
- Warburg
- Warburg
- Bounded Warburg
- CPE
- Porous electrodes
- Films, PDM
- PDM
- Applications
- NLEIS. Introduction and mathematical background
- Electron Transfer reaction
- Two step reaction
- Two step reaction (continued)
- Rt and Rp estimation
- Galvanostatic simulations
- Instabilities
- Solution resistance effects
- Detection on nonlinearities using KKT
- Frumkin and Temkin isotherms
- NLEIS Experimental aspects. FFT, PSD, THD
- Application - other techniques HA, EFM