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Course10410168220 lectures

Cycloaddition

Prof. Krishna P Kaliappan · IIT Bombay

Start with lecture 1 At NPTEL

About

In this course, Diels-Alder reaction, 1,3-dipolar cycloaddition, Thermal and photochemical [2+2] cycloaddition reactions followed by synthetic applications of these reactions will be discussed in details.

Intended audience: Chemistry Masters students/Chemistry PhD students

Prerequisites: BSc (2 years completed)

Lectures

Week 1

  1. Lecture 1: Introduction to [4+2] Cycloaddition YouTube
  2. Lecture 2: Stereochemical Outcome of [4+2] Cycloaddition YouTube
  3. Lecture 3: Regiochemical Outcome of [4+2] Cycloaddition YouTube
  4. Lecture 4: Selected Examples of Diels-Alder Reaction YouTube
  5. Lecture 5: Hetero Diels-Alder reaction YouTube

Week 2

  1. Lecture 6: IMDA-Type I Diels-Alder Reaction YouTube
  2. Lecture 7: IMDA-Type II Diels-Alder Reaction YouTube
  3. Lecture 8: Retro Diels-Alder, Alder Rickert and Dehydro Diels-Alder Reaction YouTube
  4. Lecture 9: Lewis Acid Efffect and Asymmetric Diels-Alder reaction YouTube
  5. Lecture 10: Introduction to 1,3-Dipolar Cycloaddition YouTube

Week 3

  1. Lecture 11: Nitrones in 1,3-Dipolar Cycloaddition YouTube
  2. Lecture 12: Carbonyl Ylides in 1,3-Dipolar Cycloaddition YouTube
  3. Lecture 13: Azomethine Ylides and Nitrile Oxides in 1,3-Dipolar Cycloaddition YouTube
  4. Lecture 14: Azides in 1,3-Dipolar Cycloaddition and Click Chemistry YouTube
  5. Lecture 15: Diazoalkanes, Nitrile Imines, Azomethine Imines and Nitrile Ylides in 1,3-Dipolar Cycloaddition YouTube

Week 4

  1. Lecture 16: Thermal [2+2] Cycloaddition Reaction YouTube
  2. Lecture 17: Photochemical [2+2] Cycloaddition Reaction YouTube
  3. Lecture 18: Cubane Synthesis, DeMayo and Paternò-Büchi Reaction YouTube
  4. Lecture 19: Mechanistic Approaches of Cycloaddition Reaction YouTube
  5. Lecture 20: Summary of Cycloaddition Reactions YouTube

Syllabus and materials

At NPTEL, as the course publishes them.

Credits and licence

Institution
IIT Bombay
Department
Chemistry and Biochemistry
Teacher
Prof. Krishna P Kaliappan
Level
Undergraduate
Language
English
Subjects
Chemistry
Source
NPTEL
Licence
CC BY-NC-SA, as NPTEL states it. Non-commercial use only. NPTEL's terms
Attribution
NPTEL states: "Distributed under Creative Commons Attribution-ShareAlike / CC BY - NC - SA", beside a BY-NC-SA badge.
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