Course10410113660 lectures
Advanced Transition Metal Chemistry
Prof. M S Balakrishna · IIT Bombay
About
This course on "Chemistry of Transition Metals" focuses mainly on coordination chemistry, classification of ligands with special emphasis on structure and bonding concepts. 18 Electron rule and its importance in coordination and organometallic compounds. Reactions such as oxidative addition and reductive elimination, important in catalysis, are discussed in detail. Metal-ligand and metal-metal multiple bonding, trans effect in square planar complexes are also included in the discussion.
Intended audience: All UG, PG, PhD students, college lecturers and all chemistry researchers.
Prerequisites: 12th Grade Chemistry Knowledge.INTENDED AUDIENCE: All UG, PG, PhD students, college lecturers and all chemistry researchers.
Lectures
Week 1
- Lecture 1 : History of Periodic Table -1
- Lecture 2 : History of Periodic Table -2
- Lecture 3 : History of Periodic Table -3
- Lecture 4 : Introduction to Transition elements -1
- Lecture 5 : Introduction to Transition elements -2
Week 2
- Lecture 6 : Introduction to Transition elements -3
- Lecture 7 : Introduction to Transition elements -4
- Lecture 8 : Coordination Theory
- Lecture 9 : Werner’s Coordination Theory
- Lecture 10 : Early Bonding Concepts
Week 3
- Lecture 11 : Valence Bond Theory (VBT) -1
- Lecture 12 : Valence Bond Theory (VBT) -2
- Lecture 13 : Background To Crystal Field Theory (CFT)
- Lecture 14 : Crystal Field Theory (CFT) Jahn-Teller Theorem
- Lecture 15 : Crystal Field Theory (CFT) -1
Week 4
- Lecture 16 : Crystal Field Theory (CFT) -2
- Lecture 17 : Ligand Field Theory (LFT) -1
- Lecture 18 : Ligand Field Theory (LFT) -2
- Lecture 19 : Ligand Field Theory (LFT) -3
- Lecture 20 : Ligand Field Theory (LFT) -4
Week 5
- Lecture 21 : 18 Electron Rule
- Lecture 22 : 18 Electron Rule Lecture 22 : 18 Electron Rule
- Lecture 23 : Metal—Metal Multiple Bonds
- Lecture 24 : Metal—Metal Multiple Bonds [Quadruple and Quintuple Bonding]
- Lecture 25 : Preparation of metal Complexes
Week 6
- Lecture 26 : Preparation of metal Complexes
- Lecture 27 : Classification of ligands by donor atoms
- Lecture 28 : Classification of ligands by donor atoms- Hydrogen
- Lecture 29 : Classification of ligands by donor atoms- Carbon-1
- Lecture 30 : Classification of ligands by donor atoms- Carbon-2
Week 7
- Lecture 31 : Classification of ligands by donor atoms- Carbon-3
- Lecture 32 : Classification of ligands by donor atoms- Carbon-4
- Lecture 33 : Classification of ligands by donor atoms- Nitrogen -1
- Lecture 34 : Classification of ligands by donor atoms- Nitrogen -2
- Lecture 35 : Classification of ligands by donor atoms- Nitrogen-3
Week 8
- Lecture 36 : Classification of ligands by donor atoms- Oxygen, Phosphorus
- Lecture 37 : Classification of ligands by donor atoms- Phosphorus-1
- Lecture 38 : Classification of ligands by donor atoms- Phosphorus-2
- Lecture 39 : Classification of ligands by donor atoms- Phosphorus-3
- Lecture 40 : Classification of ligands by donor atoms- Halogens
Week 9
- Lecture 41 : Oxidative addition & reductive elimination reactions-1
- Lecture 42 : Oxidative addition & reductive elimination reactions-2
- Lecture 43 : Oxidative addition & reductive elimination reactions-3
- Lecture 44 : Oxidative addition & reductive elimination reactions-4
- Lecture 45 : Inorganic Reaction Mechanisms
Week 10
- Lecture 46 : Inorganic Reaction Mechanisms Square planar complexes
- Lecture 47 : Trans-Effect
- Lecture 48 : Substitution Reactions in Square Planar Complexes, Trans-Effect
- Lecture 49 : Substitution Reactions in Octahedral Complexes
- Lecture 50 : Substitution Reactions in Octahedral Complexes; Stereochemistry of Products
Week 11
- Lecture 51 : Electron-Transfer Processes
- Lecture 52 : Electron-Transfer Processes
- Lecture 53 : Methods of Characterization UV-Visible Spectroscopy
- Lecture 54 : Methods of Characterization UV-Visible Spectroscopy
- Lecture 55 : UV-Visible Spectroscopy
Week 12
Syllabus and materials
At NPTEL, as the course publishes them.
Credits and licence
- Institution
- IIT Bombay
- Department
- Chemistry and Biochemistry
- Teacher
- Prof. M S Balakrishna
- Level
- Undergraduate
- Language
- English
- Subjects
- Chemistry
- Source
- NPTEL
- Licence
- CC BY-NC-SA, as NPTEL states it. Non-commercial use only. NPTEL's terms
- Attribution
- NPTEL states: "Distributed under Creative Commons Attribution-ShareAlike / CC BY - NC - SA", beside a BY-NC-SA badge.
- Who can watch
- NPTEL gives no rating. Invisible Network shows it to Tweens profiles and older, judged from what the source says about it. How courses are placed