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Lecture 14 of 47Week 3

Lecture 14 : Critique of kinetic theory of collisions

Prof. Amber Jain · IIT Bombay

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Chemical kinetics and transition state theory, IIT Bombay (at NPTEL)
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All the lectures

  1. Lecture 1 : Rate: the reaction velocity Video
  2. Lecture 2 : Its elementary - rate law equations Video
  3. Lecture 3 : Arrhenius equation: what's the fuss about? Video
  4. Lecture 4 : Dance of atoms: from Newton to Hamilton Video
  5. Lecture 5 : Boltzmann distribution: a story of Hamilton, Liouville and Boltzmann Video
  6. Lecture 6 : Maxwell Boltzmann distribution: how fast are molecules moving? Video
  7. Lecture 7 : Kinetic theory of collisions: initial estimate Video
  8. Lecture 8 : Boltzmann distribution and kinetic theory of collisions Video
  9. Lecture 9 : Kinetic theory of collisions: a discussion Video
  10. Lecture 10 : Kinetic theory of collisions: reactive cross section Video
  11. Lecture 11 : Problem solving session 1 Video
  12. Lecture 12 : Problem solving session 2 Video
  13. Lecture 13 : Kinetic theory of collision and equilibrium constant Video
  14. Lecture 14 : Critique of kinetic theory of collisions Video
  15. Lecture 15 : Transition state theory and partition functions Video
  16. Lecture 16 : Partitioning the partition function Video
  17. Lecture 17 : Translating, rotating and vibrating quantum mechanically Video
  18. Lecture 18 : Partition function and equilibrium constant Video
  19. Lecture 19 : What is a transition state? Video
  20. Lecture 20 : A puzzle: cars on highway Video
  21. Lecture 21 : Transition state theory: derivation 1 Video
  22. Lecture 22 : Practical calculation of TST rate Video
  23. Lecture 23 : Calculating TST rate for the reaction H+HBr Video
  24. Lecture 24 : Collision theory as a special case of TST Video
  25. Lecture 25 : TST: an intuitive proof in one dimension Video
  26. Lecture 26 : Rate as a flux across a dividing surface Video
  27. Lecture 27 : Transition state theory: derivation 2 from dynamical perspective Video
  28. Lecture 28 : Discussion of the assumptions of TST Video
  29. Lecture 29 : Thermodynamic formulation of TST Video
  30. Lecture 30 : Problem solving session 3 Video
  31. Lecture 31 : Problem solving session 4 Video
  32. Lecture 32 : Hills and valleys of potential energy surfaces Video
  33. Lecture 33 : Molecular dynamics: rolling spheres on potential energy surfaces Video
  34. Lecture 34 : Predictions from potential energy surfaces - rotational vs vibrational energies Video
  35. Lecture 35 : Free energy and potential of mean force Video
  36. Lecture 36 : Transmission coefficient and molecualr dynamics Video
  37. Lecture 37 : Problem solving session 5 Video
  38. Lecture 38 : Microcanonical rate constant: putting balls in jars Video
  39. Lecture 39 : Microcanonical rate constant: RRK model Video
  40. Lecture 40 : Microcanonical rate constant: magic of Marcus - RRKM model Video
  41. Lecture 41 : Canonical TST from micrononical RRKM model Video
  42. Lecture 42 : Sum and density of states Video
  43. Lecture 43 : Unimolecular decay - revisited Video
  44. Lecture 44 : Unimolecular decay: RRK's approach Video
  45. Lecture 45 : Unimolecular decay: RRKM's approach Video
  46. Lecture 46 : Problem solving session 6 Video
  47. Live Session 02-03-2021 Video