Learn · Interfacial Engineering
Lecture 12 of 40week-03
Work of cohesion, adhesion, and spreading coefficient
Prof. Manigandan · IIT Ropar
Credits and licence
- From
- Interfacial Engineering, IIT Ropar (at NPTEL)
- Licence
- CC BY-NC-SA, as NPTEL states it. Non-commercial use only.
- Attribution
- NPTEL states: "Distributed under Creative Commons Attribution-ShareAlike / CC BY - NC - SA", beside a BY-NC-SA badge. Coordinated by IIT Madras.
- Who can watch
- Tweens profiles and older. How courses are placed
All the lectures
- Introduction to interfaces
- Importance of surface; Application of interfaces
- Basics of classical and emerging tools
- Concepts of capillarity and surface tension (ST) and measurement of ST and contact angle
- Overview of various surface tension measurement techniques
- Young-Dupre equation; Tutorial
- Young-Laplace equation; Tutorial
- Kelvin equation; Tutorial
- Contact angle for ideal and non-ideal cases; Application of Young-Dupre
- Measurement of contact angle of surfaces at fluid-fluid interfaces
- Washburn approach; Tutorial
- Work of cohesion, adhesion, and spreading coefficient
- Girifalco-Good Fowkes equation; Tutorial
- Demonstration of force tensiometer
- Demonstration of optical tensiometer
- Shapes of micelles, critical micelle concentration (CMC); critical packing parameter (CPP)
- Thermodynamic principles of self-assembly
- Micellar-enhanced ultrafiltration (MEUF): A surfactant-based separation technique
- HLB guidelines; Debye plot
- Surface excess concepts and problem solving
- Gibbs adsorption isotherm equation
- Deposition of Langmuir Blodgett (LB) films;Adsorption from solution
- Demonstration of double barrier LB deposition technique
- Emulsion and microemulsion; Application of microemulsion
- Demonstration of emulsification using several emulsifying devices
- Demonstration of particle size analyzer
- Demonstration of particle/droplet tracking using an inverted microscope
- Introduction to colloids
- Understanding Intermolecular forces
- van der Waals force
- Lifshitz approach
- Electrical double layer (EDL) interaction (Helmholtz)
- Gouy-Chapman EDL Model
- Gouy-Chapman-Stern EDL model
- Overlapping double layer interaction
- Derjaguin approximation; DLVO forces of interactions
- Force-measuring techniques: Direct and indirect measurements
- Steric (Polymer-mediated) forces
- Electrokinetic phenomena
- Demonstration of zeta potential measurements