Lecture 23 of 40Module 4: Thermodynamics of solutions
Activity Coefficient from Excess Property
Prof. G.K. Suraishkumar · IIT Madras
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All the lectures
- Introduction and Review
- Need for Analysis Additional Thermodynamic Functions State and Path Variables
- Equations for a Closed system Chemical Potential Concept Gibbs-Duhem Equation
- Maxwell’s relations
- Inter-Relationships between Thermodynamic Variables
- Some Useful Mathematical Manipulations
- Thermodynamic Relations for a Closed System with 1 mole of a pure Substances
- Maximum Work,Lost Work Review of Closed Systems
- Open Systems
- Equations of State - Virial Equations
- Equations of State - Cubic Equations
- Volume Estimation
- Volume Estimation (cont.,)Generalized correlations
- Generalized correlations(cont)Residual Properties
- Residual Properties(cont.,)
- Generalized Correlations and Residual Properties
- Fugacity Coefficient Estimation
- Review of Module 3
- Learning Aspects Chemical Potential Formulations
- Lewis and Randall rule partial Molar Properties
- Partial Molar Property Estimation from Mixing Experiments
- Partial Molar Property Estimation (cont.,) Excess Property
- Activity Coefficient from Excess Property
- Activity Coefficient from Excess Property (cont.,)
- Activity Coefficient from Excess Property(cont.,) Models for Activity Coefficient in Binary Systems
- Models for Activity Coefficient in Binary Systems(cont.,)
- Review of Module 4
- Criteria for Phase Equilibrium Phase Rule for Non-reacting Biosystems
- Clausius - Clayperon Equation
- Clausius - Clayperon Equation(cont.,)vapour-Liquid Equilibrium
- Vapour-Liquid Equilibrium(cont.,) Estimation of Fugacity coefficient from Equilibrium P-V-T Data
- Liquid/Liquid and Solid/Liquid Equilibria
- Review of Module 5
- Criteria for Bio-reaction Equilibria
- Phase rule for Reacting Biosystems Equilibrium constants
- Effect of Temperature and Pressure on the Equilibrium constants
- Reaction in Liquid or Solid Phases
- Free energy Changes for some Bioreactions
- Electrolytes
- Course Review