Opening the book…
Given that P(x) is the probability density of the electron at position x, we can determine the average, or expectation value of x from
\[ \langle x\rangle =\frac{\int^{+\infty}_{-\infty} xP(x)dx}{\int^{+\infty}_{-\infty} P(x)dx} \nonumber \]
Of course if the wavefunction is normalized then the denominator is 1.
We could also write this in terms of the wavefunction
\[ \langle x\rangle =\frac{\int^{+\infty}_{-\infty} x|\psi(x)|^{2} dx}{\int^{+\infty}_{-\infty} |\psi(x)|^{2}dx} \nonumber \]
Where once again if the wavefunction is normalized then the denominator is 1.
Since \(|\psi(x)|^{2} = \psi(x)^{*}\psi(x)\),
\[ \langle x\rangle =\frac{\int^{+\infty}_{-\infty} \psi(x)^{*}x\psi(x) dx}{\int^{+\infty}_{-\infty}\psi(x)^{*}\psi(x) dx} \nonumber \]
This page titled 1.12: Expectation values of position was last modified on Sun, 22 May 2022 21:20:22 GMT and is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by Marc Baldo (MIT OpenCourseWare) via source content that was edited to the style and standards of the LibreTexts platform.
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