Structure & Reactivity IV: Reactivity in Organic, Biological and Inorganic Chemistry 2

by Chris Schaller

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Kinetics, Substitution Reactions in Organic and Inorganic Chemistry, Addition and Elimination Reactions Involving Alkenes and Aromatics

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Publisher
College of Saint Benedict/Saint John's University
Subjects
Chemistry, General Chemistry
Licence
CC BY-NC 3.0, as LibreTexts states it. Non-commercial use only.
Who can read
Tweens profiles and older, judged from its title and subjects

Contents

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  1. Front Matter
  2. TitlePage
  3. InfoPage
  4. Table of Contents
  5. Licensing
  6. 1: Reaction Kinetics
  7. 1.1: Introduction- Reaction Kinetics
  8. 1.2: Reaction Rates
  9. 1.3: Activation Barriers
  10. 1.4: Collisions and Phase
  11. 1.5: Collisions and Concentration
  12. 1.6: Rate Laws
  13. 1.7: Elementary Reactions
  14. 1.8: Catalysis
  15. 1.9: Solutions to Selected Problems
  16. 2: Mathematical Tools in Reaction Kinetics
  17. 2.1: Determination of Activation Parameters
  18. 2.2: The Rate Law Takes Different Forms
  19. 2.3: Determining the Rate Law Experimentally
  20. 2.4: Elementary Reactions and the Rate Law
  21. 2.5: Enzyme Kinetics and Inhibition
  22. 2.6: Characterization- The Mathematics Behind Enzyme Kinetics
  23. 2.7: Potential Energy Surfaces
  24. 2.8: Kinetic Isotope Effects
  25. 2.9: Linear Free Energy Relationships
  26. 2.10: Solutions to Selected Problems
  27. 3: Ligand Substitution in Coordination Complexes
  28. 3.1: Introduction to Substitution
  29. 3.2: Mechanistic Possibilities
  30. 3.3: Associative Mechanism and Kinetics
  31. 3.4: Dissociative Mechanism and Kinetics
  32. 3.5: Activation Parameters
  33. 3.6: Some Reasons for Differing Mechanisms
  34. 3.7: The Trans Effect
  35. 3.8: Solutions to Selected Problems
  36. 4: Aliphatic Nucleophilic Substitution
  37. 4.1: Introduction to Aliphatic Nucleophilic Substitution
  38. 4.2: Mechanism of Aliphatic Nucleophilic Substitution
  39. 4.3: Aliphatic Nucleophilic Substitution - Rate Laws
  40. 4.4: Stereochemistry
  41. 4.5: Regiochemistry
  42. 4.6: Structural Factors Influencing the Mechanism
  43. 4.7: Solvent Effects
  44. 4.8: Nucleophilicity
  45. 4.9: Enolate Nucleophiles
  46. 4.10: Leaving Group Formation
  47. 4.11: Addition to Strained Rings - Epoxides
  48. 4.12: Elimination
  49. 4.13: Regiochemistry in Elimination
  50. 4.14: Stereochemistry in Elimination
  51. 4.15: Factors Influencing the Elimination Mechanism
  52. 4.16: Nucleophilic Substitution in Synthesis - Alcohols and Ethers
  53. 4.17: Nucleophilic Substitution in Synthesis- Amines
  54. 4.18: Nucleophilic Substitution at Silicon
  55. 4.19: Extra Problems with Nucleophilic Substitution and Elimination
  56. 4.20: Solutions to Selected Problems
  57. 5: Oxidative Addition and Reductive Elimination
  58. 5.1: Introduction
  59. 5.2: Reaction Overview
  60. 5.3: Polar Oxidative Addition
  61. 5.4: Concerted Oxidative Addition
  62. 5.5: Oxidative Addition in Action- Catalytic Hydrogenation
  63. 5.6: Coupling Reactions in Organic Synthesis
  64. 5.7: Solutions to Selected Problems
  65. 6: Electrophilic Addition to Alkenes
  66. 6.1: Introduction to Electrophilic Addition
  67. 6.2: Cations in Electrophilic Addition
  68. 6.3: Solvent Participation in Electrophilic Addition
  69. 6.4: Stabilized Cations in Electrophilic Addition
  70. 6.5: Addition to Coordinated Alkenes
  71. 6.6: Insertion at Coordinated Alkenes
  72. 6.7: Concerted Addition to Alkenes
  73. 6.8: Epoxidation
  74. 6.9: Cyclopropanation
  75. 6.10: Alkene Oxidations
  76. 6.11: Alkene Polymerisation
  77. 6.12: Alkene Polymerisation- Living Cationic Methods
  78. 6.13: Ziegler-Natta Polymerization
  79. 6.14: Solutions for Selected Problems.
  80. 7: Electrophilic Aromatic Substitution
  81. 7.1: Introduction to Electrophilic Aromatic Substitution
  82. 7.2: Mechanism of Electrophilic Aromatic Substitution
  83. 7.3: Formation of the Electrophile
  84. 7.4: Activation and Deactivation
  85. 7.5: Directing Effects
  86. 7.6: Solutions to Selected Problems
  87. 8: Organic Synthesis
  88. 8.1: Road Maps in Total Synthesis of Natural Products
  89. Back Matter
  90. Index
  91. Glossary
  92. Detailed Licensing