Talk200831 h 8 min480×360

MIT 5.80 Small-Molecule Spectroscopy and Dynamics, Fall 2008

MIT OpenCourseWare

EducationScience

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About

The goal of this course is to illustrate the spectroscopy of small molecules in the gas phase: quantum mechanical effective Hamiltonian models for rotational, vibrational, and electronic structure; transition selection rules and relative intensities; diagnostic patterns and experimental methods for the assignment of non-textbook spectra; breakdown of the Born-Oppenheimer approximation (spectroscopic perturbations); the stationary phase approximation; nondegenerate and quasidegenerate perturbation theory (van Vleck transformation); qualitative molecular orbital theory (Walsh diagrams); the notation of atomic and molecular spectroscopy.

Instructor: Robert Field

View the complete course at: http://ocw.mit.edu/5-80F08

*NOTE: Due to technical difficulties, Lecture 32 is not available.

Album art photograph courtesy of Flickr user Jenny Spadafora. http://www.flickr.com/photos/jspad/

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MIT OpenCourseWare
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