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Advanced Thermodynamics

Prof. Nanda Kishore · IIT Guwahati

Start with lecture 1 At NPTEL

About

In any chemical process, often one encounter interaction between phases where transfer of species takes place from one phase to other. That is there exist several situations of vapor-liquid, liquid-liquid, vapor-liquid-liquid, solid-liquid equilibria in chemical engineering processes. Often these situations are dealt with assumption of ideal behavior and binary systems but in reality non-ideality and multicomponent mixtures exists and accordingly one has to deal with such situations. This course offers step-by-step understanding of required thermodynamic properties to handle such equilibrium cases and explore possible ways of solving problems associated with non-ideality in VLE, LLE, VLLE and SLE for multicomponent mixtures.

Intended audience: Chemical Engineering, Biotechnology, Petroleum Engineering, Polymer Engineering and Food Engineering

Prerequisites: UG Level Thermodynamics Course

Lectures

Week 1: Introduction of Phase Equilibria

  1. Lec 1 : Introduction of Phase Equilibrium YouTube
  2. Lec 2 : Classical Thermodynamics of Phase Equilibria YouTube
  3. Lec 3 : Classical Thermodynamics of Phase Equilibria – 2 YouTube

Week 2: Estimation of Thermodynamic Properties

  1. Lec 1: Thermodynamic Properties from Volumetric Data YouTube
  2. Lec 2: Fugacity from Volumetric Data - 1 YouTube
  3. Lec 3: Fugacity from Volumetric Data – 2 YouTube

Week 3: Potential Energy Functions and Intermolecular Forces

  1. Lec 1: Intermolecular Forces and Non-Ideal Behaviour YouTube
  2. Lec 2: Intermolecular Forces-Potential Energy Functions YouTube

Week 4: Molecular Theory of Corresponding States

  1. Lec 1: Molecular Theory of Corresponding States YouTube
  2. Lec 2: Molecular Theory of Corresponding States – 2 YouTube

Week 5: Intermolecular Interactions and E.o.S

  1. Lec 1: Intermolecular Potential and EoS YouTube
  2. Lec 2: Virial Coefficients from Potential Functions YouTube
  3. Lec 3: Virial Coefficients from Corresponding States Theory YouTube

Week 6: Gaseous Mixtures and Fugacity

  1. Lec 1: Fugacities in Gaseous Mixtures YouTube
  2. Lec 2: Fugacities in Gaseous Mixtures - 2 YouTube
  3. Lec 3: Fugacities in Gaseous Mixtures - 3 YouTube

Week 7: Liquid Mixtures and Fugacity

  1. Lec 1: Liquid Mixtures and Excess Functions YouTube
  2. Lec 2: Excess Functions and Activity Coefficients YouTube
  3. Lec 3: Activity Coefficients and Thermodynamic Consistency YouTube

Week 8: Models for Activity Coefficients using Excess Gibbs Energy

  1. Lec 1: Models for Excess Gibbs Energy YouTube
  2. Lec 2: Models for Excess Gibbs Energy - 2 YouTube
  3. Lec 3: Models for Excess Gibbs Energy - 3 YouTube

Week 9: Vapor – Liquid Equilibria of Multicomponent Non-Ideal Systems

  1. Lec 1: Vapour - Liquid Equilibrium YouTube
  2. Lec 2: Vapour - Liquid Equilibrium - 2 YouTube
  3. Lec 3: Vapour - Liquid Equilibrium - 3 YouTube

Week 10: Liquid – Liquid Equilibria of Multicomponent Non-Ideal Systems

  1. Lec 1: Liquid - Liquid Equilibrium YouTube
  2. Lec 2: Liquid - Liquid Equilibrium - 2 YouTube

Week 11: Vapor – Liquid – Liquid Equilibria of Multicomponent Non-Ideal Systems

  1. Lec 1: Vapour - Liquid - Liquid Equilibrium YouTube
  2. Lec 2: Vapour - Liquid - Liquid Equilibrium - 2 YouTube

Week 12: Solid – Liquid Equilibria of Non-Ideal Systems

  1. Lec 1: Solid - Liquid Equilibrium YouTube
  2. Lec 2: Solid - Liquid Equilibrium - 2 YouTube

Syllabus and materials

At NPTEL, as the course publishes them.

Credits and licence

Institution
IIT Guwahati
Department
Chemical Engineering
Teacher
Prof. Nanda Kishore
Level
Graduate
Language
English
Subjects
Chemistry, Engineering
Source
NPTEL
Licence
CC BY-NC-SA, as NPTEL states it. Non-commercial use only. NPTEL's terms
Attribution
NPTEL states: "Distributed under Creative Commons Attribution-ShareAlike / CC BY - NC - SA", beside a BY-NC-SA badge.
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