Opening the book…
- Chapter 1: The Chemical World
- 1.1: The Scope of Chemistry
- 1.2: Chemicals Compose Ordinary Things
- 1.3: Hypothesis, Theories, and Laws
- 1.4: The Scientific Method: How Chemists Think
- 1.5: A Beginning Chemist: How to Succeed
- Chapter 2: Measurement and Problem Solving
- 2.1: Taking Measurements
- 2.2: Scientific Notation: Writing Large and Small Numbers
- 2.3: Significant Figures: Writing Numbers to Reflect Precision
- 2.4: Significant Figures in Calculations
- 2.5: The Basic Units of Measurement
- 2.6: Problem Solving and Unit Conversions
- 2.7: Solving Multistep Conversion Problems
- 2.8: Units Raised to a Power
- 2.9: Density
- 2.10: Numerical Problem-Solving Strategies and the Solution Map
- 2.E: Measurement and Problem Solving (Exercises)
- Chapter 3: Matter and Energy
- 3.1: In Your Room
- 3.2: What is Matter?
- 3.3: Classifying Matter According to Its State: Solid, Liquid, and Gas
- 3.4: Classifying Matter According to Its Composition
- 3.5: Differences in Matter: Physical and Chemical Properties
- 3.6: Changes in Matter: Physical and Chemical Changes
- 3.7: Conservation of Mass: There is No New Matter
- 3.8: Energy
- 3.9: Energy and Chemical and Physical Change
- 3.10: Temperature: Random Motion of Molecules and Atoms
- 3.11: Temperature Changes: Heat Capacity
- 3.12: Energy and Heat Capacity Calculations
- 3.E: Exercises
- Chapter 4: Atoms and Elements
- 4.1: Experiencing Atoms at Tiburon
- 4.2: Indivisible: The Atomic Theory
- 4.3: The Nuclear Atom
- 4.4: The Properties of Protons, Neutrons, and Electrons
- 4.5: Elements: Defined by Their Numbers of Protons
- 4.6: Looking for Patterns: The Periodic Law and the Periodic Table
- 4.7: Ions: Losing and Gaining Electrons
- 4.8: Isotopes: When the Number of Neutrons Varies
- 4.9: Atomic Mass: The Average Mass of an Element’s Atoms
- Chapter 5: Molecules and Compounds
- 5.1: Sugar and Salt
- 5.2: Compounds Display Constant Composition
- 5.3: Chemical Formulas: How to Represent Compounds
- 5.4: A Molecular View of Elements and Compounds
- 5.5: Writing Formulas for Ionic Compounds
- 5.6: Nomenclature: Naming Compounds
- 5.7: Naming Ionic Compounds
- 5.8: Naming Molecular Compounds
- 5.9: Naming Acids
- 5.10: Nomenclature Summary
- 5.11: Formula Mass: The Mass of a Molecule or Formula Unit
- Chapter 6: Chemical Composition
- 6.1: How Much Sodium?
- 6.2: Counting Nails by the Pound
- 6.3: Counting Atoms by the Gram
- 6.4: Counting Molecules by the Gram
- 6.5: Chemical Formulas as Conversion Factors
- 6.6: Mass Percent Composition of Compounds
- 6.7: Mass Percent Composition from a Chemical Formula
- 6.8: Calculating Empirical Formulas for Compounds
- 6.9: Calculating Molecular Formulas for Compounds
- Chapter 7: Chemical Reactions
- 7.1: Grade School Volcanoes, Automobiles, and Laundry Detergents
- 7.2: Evidence of a Chemical Reaction
- 7.3: The Chemical Equation
- 7.4: How to Write Balanced Chemical Equations
- 7.5: Aqueous Solutions and Solubility: Compounds Dissolved in Water
- 7.6: Precipitation Reactions: Reactions in Aqueous Solution That Form a Solid
- 7.7: Writing Chemical Equations for Reactions in Solution: Molecular, Complete Ionic, and Net Ionic Equations
- 7.8: Acid–Base and Gas Evolution Reactions
- 7.9: Oxidation–Reduction Reactions
- 7.10: Classifying Chemical Reactions
- 7.11: The Activity Series
- Chapter 8: Quantities in Chemical Reactions
- 8.1: Climate Change: Too Much Carbon Dioxide
- 8.2: Stoichiometry
- 8.3: Making Molecules: Mole-to-Mole Conversions
- 8.4: Making Molecules: Mass-to-Mass Conversions
- 8.5: Limiting Reactant, Theoretical Yield, and Percent Yield
- 8.6: Limiting Reactant, Theoretical Yield, and Percent Yield from Initial Masses of Reactants
- 8.7: Enthalpy: A Measure of the Heat Evolved or Absorbed in a Reaction
- Chapter 9: Electrons in Atoms and the Periodic Table
- 9.1: Blimps, Balloons, and Models of the Atom
- 9.2: Light: Electromagnetic Radiation
- 9.3: The Electromagnetic Spectrum
- 9.4: The Bohr Model: Atoms with Orbits
- 9.5: The Quantum-Mechanical Model: Atoms with Orbitals
- 9.6: Quantum-Mechanical Orbitals and Electron Configurations
- 9.7: Electron Configurations and the Periodic Table
- 9.8: The Explanatory Power of the Quantum-Mechanical Model
- 9.9: Periodic Trends: Atomic Size, Ionization Energy, and Metallic Character
- Chapter 10: Chemical Bonding
- 10.1: Bonding Models and AIDS Drugs
- 10.2: Representing Valence Electrons with Dots
- 10.3: Lewis Structures of Ionic Compounds: Electrons Transferred
- 10.4: Covalent Lewis Structures: Electrons Shared
- 10.5: Writing Lewis Structures for Covalent Compounds
- 10.6: Resonance: Equivalent Lewis Structures for the Same Molecule
- 10.7: Predicting the Shapes of Molecules
- 10.8: Electronegativity and Polarity: Why Oil and Water Don’t Mix
- Chapter 11: Gases
- 11.1: Extra-Long Straws
- 11.2: Kinetic Molecular Theory: A Model for Gases
- 11.3: Pressure: The Result of Constant Molecular Collisions
- 11.4: Boyle’s Law: Pressure and Volume
- 11.5: Charles’s Law: Volume and Temperature
- 11.6: Gay-Lussac's Law: Temperature and Pressure
- 11.7: The Combined Gas Law: Pressure, Volume, and Temperature
- 11.8: Avogadro’s Law: Volume and Moles
- 11.9: The Ideal Gas Law: Pressure, Volume, Temperature, and Moles
- 11.10: Mixtures of Gases: Why Deep-Sea Divers Breathe a Mixture of Helium and Oxygen
- 11.11: Gases in Chemical Reactions
- Chapter 12: Liquids, Solids, and Intermolecular Forces
- 12.1: Interactions between Molecules
- 12.2: Properties of Liquids and Solids
- 12.3: Intermolecular Forces in Action: Surface Tension and Viscosity
- 12.4: Evaporation and Condensation
- 12.5: Melting, Freezing, and Sublimation
- 12.6: Types of Intermolecular Forces: Dispersion, Dipole–Dipole, Hydrogen Bonding, and Ion-Dipole
- 12.7: Types of Crystalline Solids: Molecular, Ionic, and Atomic
- 12.8: Water: A Remarkable Molecule
- Chapter 13: Solutions
- 13.1: Prelude - Tragedy in Cameroon
- 13.2: Solutions: Homogeneous Mixtures
- 13.3: Solutions of Solids Dissolved in Water: How to Make Rock Candy
- 13.4: Solutions of Gases in Water: How Soda Pop Gets Its Fizz
- 13.5: Solution Concentration: Mass Percent
- 13.6: Solution Concentration: Molarity
- 13.7: Solution Dilution
- 13.8: Solution Stoichiometry
- 13.9: Freezing Point Depression and Boiling Point Elevation: Making Water Freeze Colder and Boil Hotter
- 13.10: Osmosis: Why Drinking Salt Water Causes Dehydration
- Chapter 14: Acids and Bases
- 14.1: Sour Patch Kids and International Spy Movies
- 14.2: Acids: Properties and Examples
- 14.3: Bases: Properties and Examples
- 14.4: Molecular Definitions of Acids and Bases
- 14.5: Reactions of Acids and Bases
- 14.6: Acid–Base Titration: A Way to Quantify the Amount of Acid or Base in a Solution
- 14.7: Strong and Weak Acids and Bases
- 14.8: Water: Acid and Base in One
- 14.9: The pH and pOH Scales: Ways to Express Acidity and Basicity
- 14.10: Buffers: Solutions That Resist pH Change
- Explain the difference between a pure substance and a mixture.
- Explain the difference between an element and a compound.
- Explain the difference between a homogeneous mixture and a heterogeneous mixture.
One useful way of organizing our understanding of matter is to think of a hierarchy that extends down from the most general and complex to the simplest and most fundamental (Figure \(\PageIndex{1}\)). Matter can be classified into two broad categories: pure substances and mixtures. A pure substance is a form of matter that has a constant composition (meaning that it is the same everywhere) and properties that are constant throughout the sample (meaning that there is only one set of properties such as melting point, color, boiling point, etc. throughout the matter). A material composed of two or more substances is a mixture. Elements and compounds are both examples of pure substances. A substance that cannot be broken down into chemically simpler components is an element. Aluminum, which is used in soda cans, is an element. A substance that can be broken down into chemically simpler components (because it has more than one element) is a compound. For example, water is a compound composed of the elements hydrogen and oxygen. Today, there are about 118 elements in the known universe. In contrast, scientists have identified tens of millions of different compounds to date.
Ordinary table salt is called sodium chloride. It is considered a substance because it has a uniform and definite composition. All samples of sodium chloride are chemically identical. Water is also a pure substance. Salt easily dissolves in water, but salt water cannot be classified as a substance because its composition can vary. You may dissolve a small amount of salt or a large amount into a given amount of water. A mixture is a physical blend of two or more components, each of which retains its own identity and properties in the mixture. Only the form of the salt is changed when it is dissolved into water. It retains its composition and properties.
A homogeneous mixture is a mixture in which the composition is uniform throughout the mixture. The salt water described above is homogeneous because the dissolved salt is evenly distributed throughout the entire salt water sample. Often it is easy to confuse a homogeneous mixture with a pure substance because they are both uniform. The difference is that the composition of the substance is always the same. The amount of salt in the salt water can vary from one sample to another. All solutions are considered homogeneous because the dissolved material is present in the same amount throughout the solution.
A heterogeneous mixture is a mixture in which the composition is not uniform throughout the mixture. Vegetable soup is a heterogeneous mixture. Any given spoonful of soup will contain varying amounts of the different vegetables and other components of the soup.
A phase is any part of a sample that has a uniform composition and properties. By definition, a pure substance or a homogeneous mixture consists of a single phase. A heterogeneous mixture consists of two or more phases. When oil and water are combined, they do not mix evenly, but instead form two separate layers. Each of the layers is called a phase.
Identify each substance as a compound, an element, a heterogeneous mixture, or a homogeneous mixture (solution).
- filtered tea
- freshly squeezed orange juice
- a compact disc
- aluminum oxide, a white powder that contains a 2:3 ratio of aluminum and oxygen atoms
- selenium
Given: a chemical substance
Asked for: its classification
Strategy:
- Decide whether a substance is chemically pure. If it is pure, the substance is either an element or a compound. If a substance can be separated into its elements, it is a compound.
- If a substance is not chemically pure, it is either a heterogeneous mixture or a homogeneous mixture. If its composition is uniform throughout, it is a homogeneous mixture.
Solution
- A) Tea is a solution of compounds in water, so it is not chemically pure. It is usually separated from tea leaves by filtration.
B) Because the composition of the solution is uniform throughout, it is a homogeneous mixture. - A) Orange juice contains particles of solid (pulp) as well as liquid; it is not chemically pure.
B) Because its composition is not uniform throughout, orange juice is a heterogeneous mixture. - A) A compact disc is a solid material that contains more than one element, with regions of different compositions visible along its edge. Hence, a compact disc is not chemically pure.
B) The regions of different composition indicate that a compact disc is a heterogeneous mixture. - A) Aluminum oxide is a single, chemically pure compound.
- A) Selenium is one of the known elements.
Identify each substance as a compound, an element, a heterogeneous mixture, or a homogeneous mixture (solution).
- white wine
- mercury
- ranch-style salad dressing
- table sugar (sucrose)
- Answer a:
- homogeneous mixture (solution)
- Answer b:
- element
- Answer c:
- heterogeneous mixture
- Answer d:
- compound
How would a chemist categorize each example of matter?
- saltwater
- soil
- water
- oxygen
Solution
- Saltwater acts as if it were a single substance even though it contains two substances—salt and water. Saltwater is a homogeneous mixture, or a solution.
- Soil is composed of small pieces of a variety of materials, so it is a heterogeneous mixture.
- Water is a substance. More specifically, because water is composed of hydrogen and oxygen, it is a compound.
- Oxygen, a substance, is an element.
How would a chemist categorize each example of matter?
- coffee
- hydrogen
- an egg
- Answer a:
- a homogeneous mixture (solution), assuming it is filtered coffee
- Answer b:
- element
- Answer c:
- heterogeneous mixture
Summary
Matter can be classified into two broad categories: pure substances and mixtures. A pure substance is a form of matter that has a constant composition and properties that are constant throughout the sample. Mixtures are physical combinations of two or more elements and/or compounds. Mixtures can be classified as homogeneous or heterogeneous. Elements and compounds are both examples of pure substances. Compounds are substances that are made up of more than one type of atom. Elements are the simplest substances made up of only one type of atom.
Vocabulary
- Element: a substance that is made up of only one type of atom.
- Compound:a substance that is made up of more than one type of atom bonded together.
- Mixture: a combination of two or more elements or compounds which have not reacted to bond together; each part in the mixture retains its own properties.
Contributions & Attributions
Stephen Lower, Professor Emeritus (Simon Fraser U.) Chem1 Virtual Textbook
3.4: Classifying Matter According to Its Composition is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by LibreTexts.
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