Opening the book…
- Chapter 1: The Chemical World
- 1.1: The Scope of Chemistry
- 1.2: Chemicals Compose Ordinary Things
- 1.3: Hypothesis, Theories, and Laws
- 1.4: The Scientific Method: How Chemists Think
- 1.5: A Beginning Chemist: How to Succeed
- Chapter 2: Measurement and Problem Solving
- 2.1: Taking Measurements
- 2.2: Scientific Notation: Writing Large and Small Numbers
- 2.3: Significant Figures: Writing Numbers to Reflect Precision
- 2.4: Significant Figures in Calculations
- 2.5: The Basic Units of Measurement
- 2.6: Problem Solving and Unit Conversions
- 2.7: Solving Multistep Conversion Problems
- 2.8: Units Raised to a Power
- 2.9: Density
- 2.10: Numerical Problem-Solving Strategies and the Solution Map
- 2.E: Measurement and Problem Solving (Exercises)
- Chapter 3: Matter and Energy
- 3.1: In Your Room
- 3.2: What is Matter?
- 3.3: Classifying Matter According to Its State: Solid, Liquid, and Gas
- 3.4: Classifying Matter According to Its Composition
- 3.5: Differences in Matter: Physical and Chemical Properties
- 3.6: Changes in Matter: Physical and Chemical Changes
- 3.7: Conservation of Mass: There is No New Matter
- 3.8: Energy
- 3.9: Energy and Chemical and Physical Change
- 3.10: Temperature: Random Motion of Molecules and Atoms
- 3.11: Temperature Changes: Heat Capacity
- 3.12: Energy and Heat Capacity Calculations
- 3.E: Exercises
- Chapter 4: Atoms and Elements
- 4.1: Experiencing Atoms at Tiburon
- 4.2: Indivisible: The Atomic Theory
- 4.3: The Nuclear Atom
- 4.4: The Properties of Protons, Neutrons, and Electrons
- 4.5: Elements: Defined by Their Numbers of Protons
- 4.6: Looking for Patterns: The Periodic Law and the Periodic Table
- 4.7: Ions: Losing and Gaining Electrons
- 4.8: Isotopes: When the Number of Neutrons Varies
- 4.9: Atomic Mass: The Average Mass of an Element’s Atoms
- Chapter 5: Molecules and Compounds
- 5.1: Sugar and Salt
- 5.2: Compounds Display Constant Composition
- 5.3: Chemical Formulas: How to Represent Compounds
- 5.4: A Molecular View of Elements and Compounds
- 5.5: Writing Formulas for Ionic Compounds
- 5.6: Nomenclature: Naming Compounds
- 5.7: Naming Ionic Compounds
- 5.8: Naming Molecular Compounds
- 5.9: Naming Acids
- 5.10: Nomenclature Summary
- 5.11: Formula Mass: The Mass of a Molecule or Formula Unit
- Chapter 6: Chemical Composition
- 6.1: How Much Sodium?
- 6.2: Counting Nails by the Pound
- 6.3: Counting Atoms by the Gram
- 6.4: Counting Molecules by the Gram
- 6.5: Chemical Formulas as Conversion Factors
- 6.6: Mass Percent Composition of Compounds
- 6.7: Mass Percent Composition from a Chemical Formula
- 6.8: Calculating Empirical Formulas for Compounds
- 6.9: Calculating Molecular Formulas for Compounds
- Chapter 7: Chemical Reactions
- 7.1: Grade School Volcanoes, Automobiles, and Laundry Detergents
- 7.2: Evidence of a Chemical Reaction
- 7.3: The Chemical Equation
- 7.4: How to Write Balanced Chemical Equations
- 7.5: Aqueous Solutions and Solubility: Compounds Dissolved in Water
- 7.6: Precipitation Reactions: Reactions in Aqueous Solution That Form a Solid
- 7.7: Writing Chemical Equations for Reactions in Solution: Molecular, Complete Ionic, and Net Ionic Equations
- 7.8: Acid–Base and Gas Evolution Reactions
- 7.9: Oxidation–Reduction Reactions
- 7.10: Classifying Chemical Reactions
- 7.11: The Activity Series
- Chapter 8: Quantities in Chemical Reactions
- 8.1: Climate Change: Too Much Carbon Dioxide
- 8.2: Stoichiometry
- 8.3: Making Molecules: Mole-to-Mole Conversions
- 8.4: Making Molecules: Mass-to-Mass Conversions
- 8.5: Limiting Reactant, Theoretical Yield, and Percent Yield
- 8.6: Limiting Reactant, Theoretical Yield, and Percent Yield from Initial Masses of Reactants
- 8.7: Enthalpy: A Measure of the Heat Evolved or Absorbed in a Reaction
- Chapter 9: Electrons in Atoms and the Periodic Table
- 9.1: Blimps, Balloons, and Models of the Atom
- 9.2: Light: Electromagnetic Radiation
- 9.3: The Electromagnetic Spectrum
- 9.4: The Bohr Model: Atoms with Orbits
- 9.5: The Quantum-Mechanical Model: Atoms with Orbitals
- 9.6: Quantum-Mechanical Orbitals and Electron Configurations
- 9.7: Electron Configurations and the Periodic Table
- 9.8: The Explanatory Power of the Quantum-Mechanical Model
- 9.9: Periodic Trends: Atomic Size, Ionization Energy, and Metallic Character
- Chapter 10: Chemical Bonding
- 10.1: Bonding Models and AIDS Drugs
- 10.2: Representing Valence Electrons with Dots
- 10.3: Lewis Structures of Ionic Compounds: Electrons Transferred
- 10.4: Covalent Lewis Structures: Electrons Shared
- 10.5: Writing Lewis Structures for Covalent Compounds
- 10.6: Resonance: Equivalent Lewis Structures for the Same Molecule
- 10.7: Predicting the Shapes of Molecules
- 10.8: Electronegativity and Polarity: Why Oil and Water Don’t Mix
- Chapter 11: Gases
- 11.1: Extra-Long Straws
- 11.2: Kinetic Molecular Theory: A Model for Gases
- 11.3: Pressure: The Result of Constant Molecular Collisions
- 11.4: Boyle’s Law: Pressure and Volume
- 11.5: Charles’s Law: Volume and Temperature
- 11.6: Gay-Lussac's Law: Temperature and Pressure
- 11.7: The Combined Gas Law: Pressure, Volume, and Temperature
- 11.8: Avogadro’s Law: Volume and Moles
- 11.9: The Ideal Gas Law: Pressure, Volume, Temperature, and Moles
- 11.10: Mixtures of Gases: Why Deep-Sea Divers Breathe a Mixture of Helium and Oxygen
- 11.11: Gases in Chemical Reactions
- Chapter 12: Liquids, Solids, and Intermolecular Forces
- 12.1: Interactions between Molecules
- 12.2: Properties of Liquids and Solids
- 12.3: Intermolecular Forces in Action: Surface Tension and Viscosity
- 12.4: Evaporation and Condensation
- 12.5: Melting, Freezing, and Sublimation
- 12.6: Types of Intermolecular Forces: Dispersion, Dipole–Dipole, Hydrogen Bonding, and Ion-Dipole
- 12.7: Types of Crystalline Solids: Molecular, Ionic, and Atomic
- 12.8: Water: A Remarkable Molecule
- Chapter 13: Solutions
- 13.1: Prelude - Tragedy in Cameroon
- 13.2: Solutions: Homogeneous Mixtures
- 13.3: Solutions of Solids Dissolved in Water: How to Make Rock Candy
- 13.4: Solutions of Gases in Water: How Soda Pop Gets Its Fizz
- 13.5: Solution Concentration: Mass Percent
- 13.6: Solution Concentration: Molarity
- 13.7: Solution Dilution
- 13.8: Solution Stoichiometry
- 13.9: Freezing Point Depression and Boiling Point Elevation: Making Water Freeze Colder and Boil Hotter
- 13.10: Osmosis: Why Drinking Salt Water Causes Dehydration
- Chapter 14: Acids and Bases
- 14.1: Sour Patch Kids and International Spy Movies
- 14.2: Acids: Properties and Examples
- 14.3: Bases: Properties and Examples
- 14.4: Molecular Definitions of Acids and Bases
- 14.5: Reactions of Acids and Bases
- 14.6: Acid–Base Titration: A Way to Quantify the Amount of Acid or Base in a Solution
- 14.7: Strong and Weak Acids and Bases
- 14.8: Water: Acid and Base in One
- 14.9: The pH and pOH Scales: Ways to Express Acidity and Basicity
- 14.10: Buffers: Solutions That Resist pH Change
- Define density.
- Use density as a conversion factor.
Density (\(\rho\)) is a physical property found by dividing the mass of an object by its volume. Regardless of the sample size, density is always constant. For example, the density of a pure sample of tungsten is always 19.25 grams per cubic centimeter. This means that whether you have one gram or one kilogram of the sample, the density will never vary. The equation, as we already know, is as follows:
\[\text{Density}=\dfrac{\text{Mass}}{\text{Volume}} \nonumber \]
or just
\[\rho =\dfrac{m}{V} \label{eq2} \]
Based on this equation, it's clear that density can, and does, vary from element to element and substance to substance due to differences in the relationship of mass and volume. Pure water, for example, has a density of 0.998 g/cm3 at 25° C. The average densities of some common substances are in Table \(\PageIndex{1}\). Notice that corn oil has a lower mass to volume ratio than water. This means that when added to water, corn oil will “float.”
| Substance | Density at 25°C (g/cm3) |
|---|---|
| blood | 1.035 |
| body fat | 0.918 |
| whole milk | 1.030 |
| corn oil | 0.922 |
| mayonnaise | 0.910 |
| honey | 1.420 |
Density can be measured for all substances—solids, liquids and gases. For solids and liquids, density is often reported using the units of g/cm3. Densities of gases, which are significantly lower than the densities of solids and liquids, are often given using units of g/L.
Calculate the density of a 30.2 mL sample of ethyl alcohol with a mass of 23.71002 g
Solution
This is a direct application of Equation \ref{eq2}:
\[\rho = \dfrac{23.71002\,g}{30.2\,mL} = 0.785\, g/mL \nonumber \]
- Find the density (in kg/L) of a sample that has a volume of 36.5 L and a mass of 10.0 kg.
- If you have a 2.130 mL sample of acetic acid with mass 0.002234 kg, what is the density in kg/L?
- Answer a
- \(0.274 \,kg/L\)
- Answer b
- \(1.049 \,kg/L\)
Density as a Conversion Factor
Conversion factors can also be constructed for converting between different kinds of units. For example, density can be used to convert between the mass and the volume of a substance. Consider mercury, which is a liquid at room temperature and has a density of 13.6 g/mL. The density tells us that 13.6 g of mercury have a volume of 1 mL. We can write that relationship as follows:
13.6 g mercury = 1 mL mercury
This relationship can be used to construct two conversion factors:
\[\dfrac{13.6\:g}{1\:mL} = 1 \nonumber \]
and
\[\dfrac{1\:mL}{13.6\:g} = 1 \nonumber \]
Which one do we use? It depends, as usual, on the units we need to cancel and introduce. For example, suppose we want to know the mass of 2.0 mL of mercury. We would use the conversion factor that has milliliters on the bottom (so that the milliliter unit cancels) and grams on top, so that our final answer has a unit of mass:
\[\mathrm{2.0\:\cancel{mL}\times\dfrac{13.6\:g}{1\:\cancel{mL}}=27.2\:g=27\:g} \nonumber \]
In the last step, we limit our final answer to two significant figures because the volume quantity has only two significant figures; the 1 in the volume unit is considered an exact number, so it does not affect the number of significant figures. The other conversion factor would be useful if we were given a mass and asked to find volume, as the following example illustrates.
Density can be used as a conversion factor between mass and volume.
A mercury thermometer for measuring a patient’s temperature contains 0.750 g of mercury. What is the volume of this mass of mercury?
Solution
| Steps for Problem Solving | Unit Conversion |
|---|---|
| Identify the "given" information and what the problem is asking you to "find." |
Given: 0.750 g Find: mL |
| List other known quantities. | 13.6 g/mL (density of mercury) |
| Prepare a concept map. | ![]() |
| Calculate. |
\[ 0.750 \; \cancel{\rm{g}} \times \dfrac{1\; \rm{mL}}{13.6 \; \cancel{\rm{g}}} = 0.055147 ... \; \rm{mL} \approx 0.0551\; \rm{mL} \nonumber \] We have limited the final answer to three significant figures. |
What is the volume of 100.0 g of air if its density is 1.3 g/L?
- Answer
- \(77 \, L\)
Summary
- Density is defined as the mass of an object divided by its volume.
- Density can be used as a conversion factor between mass and volume.
2.9: Density is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by LibreTexts.
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