6.4: Particle-Wave Duality: Prelude to Quantum Mechanics

Chem 1402:General Chemistry I · LibreTexts

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    6.4: Particle-Wave Duality: Prelude to Quantum Mechanics

    de Broglie Wavelength

    Exercise \(\PageIndex{1}\)

    For a proton (mass = 1.673 × 10–27 kg) moving with a velocity of 8.63 × 104 m/s, what is the de Broglie wavelength of the proton (in pm)?

    Answer

    4.59 pm

    \[E = \frac{1}{2}mv^{2}\]

    \[E = \frac{1}{2}(1.673*10^{-27})(8.63*10^{4})^{2} = 6.229*10^{-18}\;J\]

    \[\lambda = \frac{h}{\sqrt{2Em}}\]

    \[\lambda = \frac{6.626*10^{-34}}{\sqrt{2*(6.229*10^{-18})*(1.673*10^{-27})}}\]
    \[\lambda = 4.588*10^{-12}\;m=4.588\;pm\]

    Exercise \(\PageIndex{1}\)

    What is the de Broglie wavelength of an electron traveling at 15.9% of the speed of light?  (c  = 3.00  × 108 m/s, h =  6.63 × 10–34 J·s, me  =  9.109 × 10–31 J)

    Answer

    1.52 × 10–11 m

    Exercise \(\PageIndex{1}\)

    If the de Broglie wavelength of an electron is 90.2 nm, what is its velocity? (The mass of an electron is 9.11 × 10–31 kg.)

    Answer

    8.06 × 103 m/s

    Exercise \(\PageIndex{1}\)

    What is the de Broglie wavelength of a 250-g baseball traveling at 85 mph?  (1 mi = 1.609 km and h =  6.63 × 10–34 J·s)

    Answer

    7.0 × 10-35 m


    6.4: Particle-Wave Duality: Prelude to Quantum Mechanics is shared under a CC BY-NC-SA 4.0 license and was authored, remixed, and/or curated by LibreTexts.