Chem 260: Inorganic Chemistry

by Steven N. Girard

Inorganic chemistry deals with the synthesis and behavior of inorganic and organometallic compounds and covers all chemical compounds except the myriad organic compounds (carbon-based compounds), which are the subjects of organic chemistry. Inorganic chemistry has applications in every aspect of the chemical industry, including catalysis, materials science, pigments, surfactants, coatings, medications, fuels, and agriculture.

Description from LibreTexts.

Publisher
University of Wisconsin - Whitewater
Subjects
Chemistry
Licence
CC BY-SA, as LibreTexts states it
Who can read
Tweens profiles and older, judged from its title and subjects

Contents

LibreTexts writes equations in TeX, and here they show as TeX; the PDF has them typeset.

  1. Front Matter
  2. TitlePage
  3. InfoPage
  4. Table of Contents
  5. Licensing
  6. 1: Review of Chemical Bonding
  7. 1.1: Prelude to Chemical Bonding
  8. 1.2: Waves and Electromagnetic Radiation
  9. 1.3: Quantization of Energy
  10. 1.4: Atomic Orbitals and Their Energies
  11. 1.5: Slater's Rules
  12. 1.6: References
  13. 2: Molecular Orbital Theory
  14. 2.1: Valence Bond Theory- Lewis Dot Structures, the Octet Rule, Formal Charge, Resonance, and the Isoelectronic Principle
  15. 2.2: The Shapes of Molecules (VSEPR Theory) and Orbital Hybridization
  16. 2.3: Prelude to Molecular Orbital Theory
  17. 2.4: Molecular Orbital Theory
  18. 2.5: Constructing Molecular Orbitals from Atomic Orbitals
  19. 2.6: Orbital Symmetry
  20. 2.7: σ, π, and δ orbitals
  21. 2.8: Diatomic Molecules
  22. 2.9: Orbital Filling
  23. 2.10: Second-Row Diatomic Molecules
  24. 2.11: Periodic Trends in π Bonding
  25. 2.12: References
  26. 3: Coordination Chemistry
  27. 3.1: History of Coordination Compounds
  28. 3.2: Metal Complexes
  29. 3.3: Ligands with more than one Donor Atom
  30. 3.4: Nomenclature of Coordination Chemistry
  31. 3.5: Isomerization
  32. 3.6: Enantiomers in Octahedral Complexes with Bidentate Ligands
  33. 3.7: Structural Isomers- Coordination Isomerism in Transition Metal Complexes
  34. 3.8: Structural Isomers- Ionization Isomerism in Transition Metal Complexes
  35. 3.9: Structural Isomers- Linkage Isomerism in Transition Metal Complexes
  36. 3.10: Color and Magnetism
  37. 4: Coordination Chemistry and Crystal Field Theory
  38. 4.1: Prelude to Coordination Chemistry and Crystal Field Theory
  39. 4.2: Chelate and Macrocyclic Effects
  40. 4.3: Ligand Substitution Reactions
  41. 4.4: Counting Electrons in Transition Metal Complexes
  42. 4.5: Crystal Field Theory
  43. 4.6: Spectrochemical Series
  44. 4.7: π-Bonding between Metals and Ligands
  45. 4.8: Crystal Field Stabilization Energy, Pairing, and Hund's Rule
  46. 4.9: Magnetic Susceptibility and the Spin-only Formula
  47. 4.10: Jahn-Teller Distortions
  48. 4.11: Non-octahedral Complexes
  49. 4.12: Tetrahedral Complexes
  50. 4.13: Stability of Transition Metal Complexes
  51. 4.14: Ligand Field Theory
  52. 4.15: The 18-electron Rule
  53. 4.16: References
  54. 5: Thermodynamics of Lattices
  55. 5.1: Lattice Energy
  56. 5.2: Lattice Energy- The Born-Haber cycle
  57. 5.3: Lattice Enthalpies and Born Haber Cycles
  58. 5.4: The Born-Lande' equation
  59. 6: Acid-Base Chemistry
  60. 6.1: Prelude to Acid-Base Chemistry
  61. 6.2: Brønsted and Lewis Acids and Bases
  62. 6.3: Molecular Structure and Acid-Base Behavior
  63. 6.4: Oxides
  64. 6.5: Lewis Acids and Bases
  65. 6.6: Hard and Soft Acids and Bases
  66. 6.7: References
  67. 7: Molecular Symmetry
  68. 7.1: Introduction
  69. 7.2: Symmetry Operations and Elements
  70. 7.3: Symmetry Elements
  71. 7.4: Successive Operations
  72. 7.5: Point Groups
  73. 7.6: Character Tables - An Introduction
  74. 8: Solids
  75. 8.1: The Solid State of Matter
  76. 8.2: Lattice Structures in Crystalline Solids
  77. 8.3: Simple Cubic
  78. 8.4: Body Centered Packing
  79. 8.5: Metal Structures
  80. 8.6: Solids
  81. 8.7: Sphere Packing
  82. 8.8: Tetrahedral and Octahedral Sites
  83. 9: Electronic Properties of Materials - Superconductors and Semiconductors
  84. 9.1: Prelude to Electronic Properties of Materials - Superconductors and Semiconductors
  85. 9.2: Bonding in Metals
  86. 9.3: Band Theory of Solids
  87. 9.4: Semiconductors and Doping
  88. 9.5: Resistivity
  89. 9.6: Metal-Insulator Transitions
  90. 9.7: Superconductors
  91. 9.8: Periodic Trends- Metals, Semiconductors, and Insulators
  92. 9.9: Semiconductors- Band Gaps, Colors, Conductivity and Doping
  93. 9.10: Semiconductor p-n Junctions
  94. 9.11: Diodes, LEDs and Solar Cells
  95. 9.12: Amorphous Semiconductors
  96. 9.13: References
  97. 10: Metals and Alloys- Structure, Bonding, Electronic and Magnetic Properties
  98. 10.1: Prelude to Metals and Alloys
  99. 10.2: Unit Cells and Crystal Structures
  100. 10.3: Bravais Lattices
  101. 10.4: Crystal Structures of Metals
  102. 10.5: Bonding in Metals
  103. 10.6: Conduction in Metals
  104. 10.7: Atomic Orbitals and Magnetism
  105. 10.8: Ferro-, Ferri- and Antiferromagnetism
  106. 10.9: Hard and Soft Magnets
  107. 10.10: Discussion Questions
  108. 10.11: Problems
  109. 10.12: References
  110. 11: Basic Science of Nanomaterials
  111. 11.1: Prelude to Basic Science of Nanomaterials
  112. 11.2: Physics and Length Scales- Cavity Laser, Coulomb Blockade, Nanoscale Magnets
  113. 11.3: Semiconductor Quantum Dots
  114. 11.4: Synthesis of Semiconductor Nanocrystals
  115. 11.5: Surface Energy
  116. 11.6: Nanoscale Metal Particles
  117. 11.7: Applications of Nanomaterials
  118. 11.8: Discussion Questions
  119. 11.9: Problems
  120. 11.10: References
  121. Back Matter
  122. Index
  123. Index
  124. Glossary
  125. Detailed Licensing