Analytical Chemistry 2.0

by David Harvey

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Analytical chemistry spans nearly all areas of chemistry but involves the development of tools and methods to measure physical properties of substances and apply those techniques to the identification of their presence (qualitative analysis) and quantify the amount present (quantitative analysis) of species in a wide variety of settings.

Description from LibreTexts.

Publisher
DePauw University
Subjects
Chemistry
Licence
CC BY-NC-SA 4.0, as LibreTexts states it. Non-commercial use only.
Who can read
Tweens profiles and older, judged from its title and subjects

Contents

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  1. 00: Front Matter
  2. Table of Contents
  3. 1: Front Matter
  4. 1.1: TitlePage
  5. 1.2: InfoPage
  6. 1.3: Table of Contents
  7. 2: Introduction to Analytical Chemistry
  8. 2.1: What is Analytical Chemistry?
  9. 2.2: The Analytical Perspective
  10. 2.3: Common Analytical Problems
  11. 2.4: Introduction to Analytical Chemistry (Exercises)
  12. 2.5: Introduction to Analytical Chemistry (Summary)
  13. 3: Basic Tools of Analytical Chemistry
  14. 3.1: Measurements in Analytical Chemistry
  15. 3.2: Concentration
  16. 3.3: Stoichiometric Calculations
  17. 3.4: Basic Equipment
  18. 3.5: Preparing Solutions
  19. 3.6: Spreadsheets and Computational Software
  20. 3.7: The Laboratory Notebook
  21. 3.8: Basic Tools of Analytical Chemistry (Exercises)
  22. 3.9: Basic Tools of Analytical Chemistry (Summary)
  23. 4: The Vocabulary of Analytical Chemistry
  24. 4.1: Analysis, Determination, and Measurement
  25. 4.2: Techniques, Methods, Procedures, and Protocols
  26. 4.3: Classifying Analytical Techniques
  27. 4.4: Selecting an Analytical Method
  28. 4.5: Developing the Procedure
  29. 4.6: Protocols
  30. 4.7: The Importance of Analytical Methodology
  31. 4.8: The Vocabulary of Analytical Chemistry (Exercises)
  32. 4.9: The Vocabulary of Analytical Chemistry (Summary)
  33. 5: Evaluating Analytical Data
  34. 5.1: Characterizing Measurements and Results
  35. 5.2: Characterizing Experimental Errors
  36. 5.3: Propagation of Uncertainty
  37. 5.4: The Distribution of Measurements and Results
  38. 5.5: Statistical Analysis of Data
  39. 5.6: Statistical Methods for Normal Distributions
  40. 5.7: Detection Limits
  41. 5.8: Using Excel and R to Analyze Data
  42. 5.9: Evaluating Analytical Data (Exercises)
  43. 5.10: Evaluating Analytical Data (Summary)
  44. 6: Standardizing Analytical Methods
  45. 6.1: Analytical Standards
  46. 6.2: Calibrating the Signal
  47. 6.3: Determining the Sensitivity
  48. 6.4: Linear Regression and Calibration Curves
  49. 6.5: Blank Corrections
  50. 6.6: Using Excel and R for a Regression Analysis
  51. 6.7: Standardizing Analytical Methods (Exercises)
  52. 6.8: Standardizing Analytical Methods (Summary)
  53. 7: Equilibrium Chemistry
  54. 7.1: Reversible Reactions and Chemical Equilibria
  55. 7.2: Thermodynamics and Equilibrium Chemistry
  56. 7.3: Manipulating Equilibrium Constants
  57. 7.4: Equilibrium Constants for Chemical Reactions
  58. 7.5: Le Châtelier’s Principle
  59. 7.6: Ladder Diagrams
  60. 7.7: Solving Equilibrium Problems
  61. 7.8: Buffer Solutions
  62. 7.9: Activity Effects
  63. 7.10: Using Excel and R to Solve Equilibrium Problems
  64. 7.11: Some Final Thoughts on Equilibrium Calculations
  65. 7.12: Equilibrium Chemistry (Exercises)
  66. 7.13: Equilibrium Chemistry (Summary)
  67. 8: Collecting and Preparing Samples
  68. 8.1: The Importance of Sampling
  69. 8.2: Designing a Sampling Plan
  70. 8.3: Implementing the Sampling Plan
  71. 8.4: Separating the Analyte from Interferents
  72. 8.5: General Theory of Separation Efficiency
  73. 8.6: Classifying Separation Techniques
  74. 8.7: Liquid–Liquid Extractions
  75. 8.8: Separation Versus Preconcentration
  76. 8.9: Collecting and Preparing Samples (Exercises)
  77. 8.10: Collecting and Preparing Samples (Summary)
  78. 9: Gravimetric Methods
  79. 9.1: Overview of Gravimetric Methods
  80. 9.2: Precipitation Gravimetry
  81. 9.3: Volatilization Gravimetry
  82. 9.4: Particulate Gravimetry
  83. 9.5: Gravimetric Methods (Exercises)
  84. 9.6: Gravimetric Methods (Summary)
  85. 10: Titrimetric Methods
  86. 10.1: Overview of Titrimetry
  87. 10.2: Acid–Base Titrations
  88. 10.3: Complexation Titrations
  89. 10.4: Redox Titrations
  90. 10.5: Precipitation Titrations
  91. 10.6: Titrimetric Methods (Exercises)
  92. 10.7: Titrimetric Methods (Summary)
  93. 11: Spectroscopic Methods
  94. 11.1: Overview of Spectroscopy
  95. 11.2: Spectroscopy Based on Absorption
  96. 11.03: UV
  97. 11.3: UV/Vis and IR Spectroscopy
  98. 11.4: Atomic Absorption Spectroscopy
  99. 11.5: Emission Spectroscopy
  100. 11.6: Photoluminescence Spectroscopy
  101. 11.7: Atomic Emission Spectroscopy
  102. 11.8: Spectroscopy Based on Scattering
  103. 11.9: Spectroscopic Methods (Exercises)
  104. 11.10: Spectroscopic Methods (Summary)
  105. 12: Electrochemical Methods
  106. 12.1: Overview of Electrochemistry
  107. 12.2: Potentiometric Methods
  108. 12.3: Coulometric Methods
  109. 12.4: Voltammetric Methods
  110. 12.5: Electrochemical Methods (Exercises)
  111. 12.6: Electrochemical Methods (Summary)
  112. 13: Chromatographic
  113. 13.1: Overview of Analytical Separations
  114. 13.2: General Theory of Column Chromatography
  115. 13.3: Optimizing Chromatographic Separations
  116. 13.4: Gas Chromatography
  117. 13.5: High-Performance Liquid Chromatography
  118. 13.6: Other Forms of Liquid Chromatography
  119. 13.7: Electrophoresis
  120. 13.8: Chromatographic and Electrophoretic Methods (Exercises)
  121. 13.9: Chromatographic and Electrophoretic Methods (Summary)
  122. 14: Kinetic Methods
  123. 14.1: Kinetic Methods Versus Equilibrium Methods
  124. 14.2: Chemical Kinetics
  125. 14.3: Radiochemistry
  126. 14.4: Flow Injection Analysis
  127. 14.5: Kinetic Methods (Exercises)
  128. 14.6: Kinetic Methods (Summary)
  129. 15: Developing a Standard Method
  130. 15.1: Optimizing the Experimental Procedure
  131. 15.2: Verifying the Method
  132. 15.3: Validating the Method as a Standard Method
  133. 15.4: Using Excel and R for an Analysis of Variance
  134. 15.5: Developing a Standard Method (Exercises)
  135. 15.6: Developing a Standard Method (Summary)
  136. 16: Quality Assurance
  137. 16.1: The Analytical Perspective—Revisited
  138. 16.2: Quality Control
  139. 16.3: Quality Assessment
  140. 16.4: Evaluating Quality Assurance Data
  141. 16.5: Quality Assurance (Exercises)
  142. 17: Additional Resources
  143. 18: Back Matter
  144. Front Matter
  145. Table of Contents