Structure & Reactivity V: Reactivity in Organic, Biological and Inorganic Chemistry 3

by Chris Schaller

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Redox Reactions, Radical Reactions, Photochemistry, Pericyclic Reactions

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Publisher
College of Saint Benedict/Saint John's University
Subjects
Chemistry, General Chemistry
Licence
CC BY-NC 3.0, as LibreTexts states it. Non-commercial use only.
Who can read
Tweens profiles and older, judged from its title and subjects

Contents

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  1. Front Matter
  2. TitlePage
  3. InfoPage
  4. Table of Contents
  5. Licensing
  6. 1: Reduction and Oxidation Reactions
  7. 1.1: Oxidation State
  8. 1.2: Redox Reactions
  9. 1.3: Reduction Potential
  10. 1.4: Reduction Potential and Energy Levels
  11. 1.5: Factors Influencing Redox Potential
  12. 1.6: Reduction of Ores
  13. 1.7: Reduction in Batteries
  14. 1.8: Balancing Redox Reactions
  15. 1.9: Outer Sphere Electron Transfer
  16. 1.10: Inner Sphere Electron Transfer
  17. 1.11: Cyclic Voltammetry
  18. 1.12: Organic Redox
  19. 1.13: Potential and Concentrations
  20. 1.14: Solutions to Selected Problems
  21. 2: Reduction Potentials of Metal Ions in Biology
  22. 2.1: Introduction
  23. 2.2: The Effect of Charge (Local Effects)
  24. 2.3: Effect of Charge- Distal Effects, or Effects of the Medium
  25. 2.4: The Effect of pH
  26. 2.5: Hard and Soft Acid and Base Considerations
  27. 2.6: Effect of Geometry
  28. 2.7: Magnetic Measurements
  29. 2.8: Solutions for Selected Problems
  30. 3: Understanding Mechanism
  31. 3.1: Intermediates
  32. 3.2: Energetics
  33. 3.3: Arrow Conventions
  34. 3.4: Solutions to Selected Problems
  35. 4: Oxygen Binding and Reduction
  36. 4.1: Introduction
  37. 4.2: Oxygen Binding
  38. 4.3: Oxygen Reduction
  39. 4.4: Metal Oxos
  40. 4.5: Solutions to Selected Problems
  41. 5: Nitrogen Reduction
  42. 5.1: Introduction to Nitrogen Reduction
  43. 5.2: The Haber-Bosch Process
  44. 5.3: Nitrogenase
  45. 5.4: Model Studies for Nitrogen Binding
  46. 5.5: Model Studies for Nitrogen Reduction
  47. 5.6: Solutions for Selected Problems
  48. 6: Radical Reactions
  49. 6.1: Introduction to Radicals
  50. 6.2: Radical Initiation- Bond Homolysis
  51. 6.3: Radical Initiation- Radical Stability
  52. 6.4: Radical Initiation- Single Electron Transfer
  53. 6.5: Radical Propagation
  54. 6.6: Radical Termination
  55. 6.7: Radical Substitution
  56. 6.8: Radical Addition
  57. 6.9: Radical Polymerization
  58. 6.10: Living Radical Polymerisation
  59. 6.11: Detection of Unpaired Electrons
  60. 6.12: Solutions for Selected Problems
  61. 7: Oxidative Phosphorylation
  62. 7.1: Introduction to Oxidative Phosphorylation
  63. 7.2: Complex I
  64. 7.3: Complex II
  65. 7.4: Complex III
  66. 7.5: Complex IV
  67. 7.6: Complex V
  68. 7.7: Solutions for Selected Problems
  69. 8: Photochemical Reactions
  70. 8.1: Absorbance
  71. 8.2: Rules of Absorbance
  72. 8.3: Fluorescence and Phosphorescence
  73. 8.4: Photolysis
  74. 8.5: Atmospheric Photochemistry- Ozone
  75. 8.6: Applications of Photochemistry- Photoredox Catalysis
  76. 8.7: Photoredox Catalysis in Organic Chemistry
  77. 8.8: Solutions to Selected Problems
  78. 9: Photosynthesis
  79. 9.1: Solutions to Selected Problems
  80. 9.2: Introduction to Photosynthesis
  81. 9.3: Photosystem II- Harvesting the Photons
  82. 9.4: Photosystem II- Electron Transfer
  83. 9.5: Photosystem II - The Oxygen-Evolving Complex
  84. 9.6: Adding a Proton Pump- Cytochrome b6f Complex
  85. 9.7: Harvesting the Photons- Photosystem I
  86. 9.8: ATP Synthase
  87. 9.9: Carbon Capture and Carbohydrate Pool
  88. 9.10: Additional Problems
  89. 10: Reactions Under Orbital Control
  90. 10.1: Introduction
  91. 10.2: Cope and Claisen Rearrangements
  92. 10.3: The Diels Alder Reaction
  93. 10.4: Regiochemistry in Diels Alder Reactions
  94. 10.5: Endo and Exo Products
  95. 10.6: Photochemical Cycloaddition
  96. 10.7: Facial Selectivity
  97. 10.8: Alkene Oxidations
  98. 10.9: Decarboxylations
  99. 10.10: Olefin Metathesis
  100. 10.11: Sigma Bond Metathesis
  101. 10.12: Solutions to Selected Problems
  102. 11: Electrophilic Rearrangement
  103. 11.1: Introduction
  104. 11.2: Pinacol Rearrangement
  105. 11.3: Baeyer-Villiger Rearrangement
  106. 11.4: Beckmann Rearrangement
  107. 11.5: Wolff Rearrangement
  108. 11.6: Solutions
  109. Back Matter
  110. Index
  111. Glossary
  112. Detailed Licensing