University of Arkansas at Little Rock: Chem 3572 Physical Chemistry for Life Sciences

by Noureen Siraj

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University of Arkansas at Little Rock
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Chemistry
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CC BY-NC-SA 4.0, as LibreTexts states it. Non-commercial use only.
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Tweens profiles and older, judged from its title and subjects

Contents

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  1. Front Matter
  2. TitlePage
  3. InfoPage
  4. Table of Contents
  5. Licensing
  6. 1: Introduction to Physical Chemistry
  7. 1.1: Nature of Physical Chemistry
  8. 1.2: Units
  9. 1.3: Atomic Mass, Molecular Mass, and the Chemical Mole
  10. 2: Properties of Gases
  11. 2.1: Some Definitions
  12. 2.2: An Operational Definition of Temperature
  13. 2.3: Ideal Gases
  14. 2.4: Real Gases
  15. 2.5: Condensation of Gases and the Critical State
  16. 2.6: Kinetic Theory of Gases
  17. 2.7: The Maxwell Distribution Laws
  18. 2.8: Molecular Collisions and the Mean Free Path
  19. 2.9: Graham's Laws of Diffusion and Effusion
  20. 2.10: Properties of Gases (Exercises)
  21. 3: The First Law of Thermodynamics
  22. 3.1: Work and Heat
  23. 3.2: The First Law of Thermodynamics
  24. 3.3: Heat Capacities
  25. 3.4: Gas Expansion
  26. 3.5: Calorimetry
  27. 3.6: Thermochemistry
  28. 3.7: Bond Energies and Bond Enthalpies
  29. 3.8: Exercises
  30. 4: The Second Law of Thermodynamics
  31. 4.1: Spontaneous Processes
  32. 4.2: Entropy
  33. 4.3: The Second Law of Thermodynamics
  34. 4.4: Entropy Changes
  35. 4.5: The Third Law of Thermodynamics
  36. 4.6: Gibbs Energy
  37. 4.7: Standard Molar Gibbs Energy of Formation
  38. 4.8: Dependence of Gibbs Energy on Temperature and Pressure
  39. 4.9: Phase Equilibria
  40. 4.10: Thermodynamics of Rubber Elasticity
  41. 4.11: Exercises
  42. 5: Solutions
  43. 5.1: Concentration Units
  44. 5.2: Partial Molar Quantities
  45. 5.3: The Thermodynamics of Mixing
  46. 5.4: Binary Mixtures of Volatile Liquids
  47. 5.5: Real Solutions
  48. 5.6: Colligative Properties
  49. 5.7: Electrolyte Solutions
  50. 5.8: Ionic Activity
  51. 5.9: Colligative Properties of Electrolyte Solutions
  52. 5.10: Biological Membranes
  53. 5.11: Solutions (Exercises)
  54. 6: Chemical Equilibrium
  55. 6.1: Chemical Equilibrium in Gaseous Systems
  56. 6.2: Reactions in Solutions
  57. 6.3: Heterogeneous Equilibria
  58. 6.4: The Influence of Temperature, Pressure, and Catalysts on the Equilibrium Constant
  59. 6.5: Binding of Ligands and Metal Ions to Macromolecules
  60. 6.6: Bioenergetics
  61. 6.7: Chemical Equilibrium (Exercises)
  62. 7: Electrochemistry
  63. 7.1: Electrochemical Cells
  64. 7.2: Single Electrode Potentials
  65. 7.3: Thermodynamics of Electrochemical Cells
  66. 7.4: Types of Electrochemical Cells
  67. 7.5: Applications of EMF Measurements
  68. 7.6: Biological Oxidation
  69. 7.7: Membrane Potential
  70. 7.8: Electrochemistry (Exercises)
  71. 8: Acids and Bases
  72. 8.1: Definitions of Acids and Bases
  73. 8.2: Acid-Base Properties of Water
  74. 8.3: Dissociation of Acids and Bases
  75. 8.4: Diprotic and Polyprotic Acids
  76. 8.5: Buffer Solutions
  77. 8.6: Acid-Base Titrations
  78. 8.7: Amino Acids
  79. 8.8: Maintaining the pH of Blood
  80. 9: Chemical Kinetics
  81. 9.1: Reaction Rates
  82. 9.2: Reaction Order
  83. 9.3: Molecularity of a Reaction
  84. 9.4: More Complex Reactions
  85. 9.5: The Effect of Temperature on Reaction Rates
  86. 9.6: Potential Energy Surfaces
  87. 9.7: Theories of Reaction Rates
  88. 9.8: Isotope Effects in Chemical Reactions
  89. 9.9: Reactions in Solution
  90. 9.10: Fast Reactions in Solution
  91. 9.11: Oscillating Reactions
  92. 9.12: Chemical Kinetics (Exercises)
  93. 10: Enzyme Kinetics
  94. 10.1: General Principles of Catalysis
  95. 10.2: The Equations of Enzyme Kinetics
  96. 10.3: Chymotrypsin as a Case Study
  97. 10.4: Multisubstrate Systems
  98. 10.5: Enzyme Inhibition
  99. 10.6: Allosteric Interactions
  100. 10.7: The Effect of pH on Enzyme Kinetics
  101. 10.8: The Effect of Temperature on Enzyme Kinetics
  102. 10.9: Exercises
  103. 11: Quantum Mechanics and Atomic Structure
  104. 11.1: The Wave Theory of Light
  105. 11.2: Planck's Quantum Theory
  106. 11.3: The Photoelectric Effect
  107. 11.4: Bohr's Theory of the Hydrogen Emission Spectrum
  108. 11.5: de Broglie's Postulate
  109. 11.6: The Heisenberg Uncertainty Principle
  110. 11.7: The Schrödinger Wave Equation
  111. 11.8: Particle in a One-Dimensional Box
  112. 11.9: Quantum-Mechanical Tunneling
  113. 11.10: The Schrödinger Wave Equation for the Hydrogen Atom
  114. 11.11: Many-Electron Atoms and the Periodic Table
  115. 11.12: Quantum Mechanics and Atomic Structure (Exercises)
  116. 12: The Chemical Bond
  117. 12.1: Lewis Structures
  118. 12.2: Valence Bond Theory
  119. 12.3: Hybridization of Atomic Orbitals
  120. 12.4: Electronegativity and Dipole Moment
  121. 12.5: Molecular Orbital Theory
  122. 12.6: Diatomic Molecules
  123. 12.7: Resonance and Electron Delocalization
  124. 12.8: Coordination Compounds
  125. 12.9: Coordination Compounds in Biological Systems
  126. 12.10: The Chemical Bond (Exercises)
  127. 13: Intermolecular Forces
  128. 13.1: Intermolecular Interactions
  129. 13.2: The Ionic Bond
  130. 13.3: Types of Intermolecular Forces
  131. 13.4: Hydrogen Bonding
  132. 13.5: The Structure and Properties of Water
  133. 13.6: Hydrophobic Interaction
  134. 13.7: Intermolecular Forces (Exercises)
  135. 14: Spectroscopy
  136. 14.1: Vocabulary
  137. 14.2: Microwave Spectroscopy
  138. 14.3: Infrared Spectroscopy
  139. 14.4: Electronic Spectroscopy
  140. 14.5: Nuclear Magnetic Resonance
  141. 14.6: Electron Spin Resonance
  142. 14.7: Fluorescence and Phosphorescence
  143. 14.8: Lasers
  144. 14.9: Optical Rotatory Dispersion and Circular Dichroism
  145. 14.10: Spectroscopy (Exercises)
  146. 15: Photochemistry and Photobiology
  147. 15.1: Introduction to Photochemistry
  148. 15.2: Photosynthesis
  149. 15.3: Vision
  150. 15.4: Biological Effects of Radiation
  151. 16: Macromolecules
  152. 16.1: Size, Shape, and Molar Mass of Macromolecules
  153. 16.2: Structure of Synthetic Polymers
  154. 16.3: Structure of Proteins and DNA
  155. 16.4: Protein Stability
  156. Back Matter
  157. Index
  158. Glossary
  159. Detailed Licensing
  160. 3: Lectures, Worksheets, and Exams
  161. 1.1: Exams
  162. 1.1.1: 2015 Exam 1 Solutions
  163. 1.1.2: 2015 Exam 2 Solutions
  164. 1.1.3: 2015 Final 1 Solutions
  165. 1.1.4: 2015 Final 2 Solutions
  166. 1.1.5: 2016 Midterm 1 Solutions
  167. 1.1.6: 2016 Midterm 2 Solutions
  168. 1.1.7: Exam 1 Review Questions
  169. 1.1.8: Exam 2 Review Questions
  170. 1.1.9: Final Review Questions
  171. 3: Worksheets
  172. 1.1: Continuous Distributions
  173. 1.1.1: Worksheet 1 Solutions
  174. 1.2: Separation of Variables
  175. 1.2.1: Worksheet 2 Solutions
  176. 1.3: Operators and Eigenvalues
  177. 1.3.1: Worksheet 3A Solutions
  178. 1.4: Particle in a Box
  179. 1.4.1: Worksheet 3B Solutions
  180. 1.5: Vibrational Spectroscopy
  181. 1.5.1: Worksheet 4A Solutions
  182. 1.6: Rotational Spectroscopy
  183. 1.6.1: Worksheet 4B Solutions
  184. 1.7: Vectors and Coordinate Systems
  185. 1.8: Angular Momentum and Commutators (L^2 corrected)
  186. 1.9: The Probabilistic Interpretation of Atomic Orbitals
  187. 1.10: Variational Method I
  188. 1.11: Variational Method II
  189. 1.12: Multi-Electron Wavefunctions
  190. 1.13: Adding Angular Momenta in Multi-Electron Atoms
  191. 1.14: The Dihydrogen Cation
  192. 1: AGENDA